Coated Diammonium Phosphate Combined With Humic Acid Improves Soil Phosphorus Availability and Photosynthesis and the Yield of Maize

Controlled release phosphorus (P) fertilizers and humic acid (HA) applications are two effective and significant techniques or measures for preventing P loss and enhancing maize development. However, the underlying physiological mechanism of how the controlled release P fertilizers combined with HA affect the maize production and P-use efficiency (PUE) remains unknown. The effects of applying coated diammonium phosphate (CDAP) and HA together on soil nutrient supply intensity, soil phosphatase activity, photosynthesis, endogenous hormone contents, and yield of maize, as well as PUE, were examined in this study. In a pot experiment, two types of P fertilizers—CDAP and diammonium phosphate (DAP)– as well as two HA application rates (0 and 45 kg ha–1) and two P levels (60 and 75 kg P2O5 ha–1) were utilized. Results showed that the key elements that influence the growth and yield of the maize were the availability of P content in soil, plant photosynthesis, and hormone levels. The combination of CDAP and HA had a greater impact on yield and PUE over the course of 2 years than either DAP alone or DAP combined with HA. Besides, using CDAP in combination with HA increased the yield and PUE by 4.2 and 8.4%, respectively, as compared to the application of CDAP alone at 75 kg P2O5 ha–1. From the twelve-leaf to milk stages, the available P content in the soil was increased by an average of 38.6% with the combination of CDAP and HA compared to the application of CDAP alone at 75 kg P2O5 ha–1. In addition, the application of CDAP combined with HA boosted the activities of ATP synthase, as well as the content of cytokinin (CTK), and hence improved the maize photosynthetic rate (Pn). When compared to the application of CDAP alone or DAP combined with HA, the Pn of CDAP + HA treatments was enhanced by 17.9–35.1% at the same P rate. In conclusion, as an environmentally friendly fertilizer, the combined application of CDAP and HA improved the intensity of the soil nutrient supply, regulated photosynthetic capabilities, and increased the yield and PUE, which is important for agricultural production, P resource conservation, and environmental protection.

Development of an ammonia production method for carbon-free energy generation

Ammonia has great prospects in the context of the transition to carbon-free energy. It can be used as fuel in gas turbines, fuel cells, internal combustion engines, and burned together with coal. However, industrial production of ammonia is based on the Haber-Bosh process, which involves the use of natural gas and coal, which, in this case, does not make it really carbon-free. This study proposes a method to produce ammonia, which is environmentally friendly and does not require the use of fossil fuels. It is based on the approach to adjusting the concentration of ammonium nitrogen in a biogas reactor and implies the sorption of ammonia from the gas phase with a solution of monoammonium phosphate, obtaining diammonium phosphate, and subsequently heating it with the release of ammonia. The factors influencing the extraction of ammonia from waste have been considered, as well as the influence of temperature on the release of ammonia from the solution of diammonium phosphate; the energy efficiency of the method has been assessed. With increasing temperature, the degree of ammonia and the degree of sorbent regeneration increased. Under laboratory conditions, 111 J/g of ammonia energy was spent. The higher the concentration of (NH4)2HPO4 in the solution, the less energy is required to obtain a unit of ammonia mass. The total amount of ammonia released varies depending on the temperature. Sorbent regeneration can be carried out using thermal energy obtained at a cogeneration plant. The possibility of using this method to produce ammonia at an industrial scale has been estimated by analyzing the ways of ammonia utilization as a fuel. The potential for ammonia production in the main livestock industries in Europe and the United States is up to 11,482,651.15 and 11,582,169.5 tons per year, respectively. Applying this solution also makes it possible to improve the efficiency of biogas production from waste with high nitrogen content. The proposed method of ammonia production could potentially contribute to the development of carbon-free energy

The effect of the type of organic matter and a source of phosphorous on the growth, yield of corn (Zea mays L.) under different levels from phosphorous in gypsum soil

A biological experiment was carried out for the purpose of knowing the effect of the type of organic matter, source and level of phosphorous on the growth and yield of corn (Zea mays L.) in gypsum soil. The experiment was carried out in one of the agricultural fields in Salah al-Din Governorate / Al-Alam district in the year 2019. The study included three factors (type of organic fertilizer, phosphorous source and phosphorous level). The factor included the type of organic fertilizer (not adding Z, compost K and sheep waste S), while the second factor included the source of phosphate fertilizer (Triple super phosphate T, diammonium phosphate D), and the third factor included phosphorous levels (0, 90, 180 and 270) kg P ha-1. The experiment was carried out in three replications according to a randomized complete block design (RCBD). Sheep manure outperformed compost in all growth and yield traits, and diammonium phosphate fertilizer outperformed Triple le super phosphate, and the level (270) kg P ha-1 was superior to the rest of the addition levels in all growth and yield traits. The interaction between sheep manure and diammonium phosphate fertilizer at the level of addition (270) kg P ha-1 gave the highest average in the dry weight of the vegetative mass after 45 and 75 days of planting, it reached (55.50 and 130.81) gm plant-1, respectively, Chlorophyll content in leaves (52.80) SPAD and grain yield reached (8119) kg ha-1.

Flame Retardancy Enhancement of Jute Fabric Using Chemical Treatment

This work aims to improve the flame retardancy of jute fabric. Raw and bleached plain weave jute fabric was used in this work. Flame retardants borax, diammonium phosphate and thiourea were applied in different concentrations in a raw and bleached jute fabric with the padding method. The influences of flame retardant finishing on the vertical flammability behaviour and tensile properties as well as wash resistance were inves¬tigated. Flame spread time was found to significantly increase when these simple flame retardant finishing agents were used. It was found that the borax-treated raw and bleached specimens exhibited higher flame spread time among all. The assessment of physical properties such as weight gain percentage and breaking load along warp and weft direction of the control and treated fabrics revealed that the increase of flame retardant finishing weight gain caused a decrease in breaking load. Furthermore, the specimens treated with borax and diammonium phosphate flame retardant showed better results than thiourea for flame retardancy and wash durability. These flame retardant jute fabrics have industrial protective textile applications as brattice cloth in mines and many other potential fields of application, e.g. flame retardant kitchen apron, furnishings for public hall, theatre and hospital, etc.

Optimal Parameters for Obtaining Diammonium Phosphate from off-balance Phosphate Raw Materials of the Karatau Basin

The article contains information about substandard material resources of phosphorite raw materials of the Republic of Kazakhstan. Samples of phosphate-siliceous raw materials of the Zhanatas Deposit were studied for the content of P2O5. To obtain diammonium phosphate (DAP), off-balance phosphorite from the Zhanatas Deposit was used, containing P2O5-16.18%. Technological solutions for the enrichment of substandard phosphate raw materials `Zhanatas` and the production of DAP from evaporated and non-evaporated WPA are proposed. Information on mineral petrographic analysis and the chemistry of the DAP production process based on the results of X-Ray Diffraction, X-Ray Phase Analysis, and SEM is provided.

Mitigation of Osmotic Stress in Cotton for the Improvement in Growth and Yield through Inoculation of Rhizobacteria and Phosphate Solubilizing Bacteria Coated Diammonium Phosphate

Cotton (Gossypium hirsutum L.) is one of the major fiber crops. Its production is under threat due to scarcity of water resources under a changing climatic scenario. Limited water availability also decreases the uptake of phosphorus, and less uptake of phosphorus can deteriorate the quality attributes of cotton fiber. There is a need to introduce bio-organic amendments which can mitigate osmotic stress on a sustainable basis. Inoculation of rhizobacteria can play an imperative role in this regard. Rhizobacteria can not only improve the growth of roots but also enhance the availability of immobile phosphorus in soil. That is why the current experiment was conducted to explore and compare the efficacy of sole application of diammonium phosphate (DAP) over plant growth-promoting rhizobacteria (PGPR) and phosphorus solubilizing bacteria (PSB) coated DAP on growth and quality attributes of cotton under artificially induced osmotic stress at flowering stage. The impact of phosphorus levels was found to be significant on the plant height, leaf area, average boll weight, stomatal conductance, net photosynthetic rate, and seed cotton yield, while the irrigation effect was significant on all the parameters. The PGPR coated phosphorus performed better as compared to other treatments under normal irrigation and osmotic stress. Results showed that PGPR coated phosphorus increased by 29.47%, 21.01%, 41.11%, 32.73%, 15.63% and 22.89% plant height, average boll weight, stomatal conductance, net photosynthetic rate, fiber length, and seed cotton yield respectively. In conclusion, PGPR coated DAP can be helpful to get higher cotton productivity as compared to control and sole application of DAP under normal irrigation and osmotic stress.