Nonlinear deterministic observer for state estimation: Application to a continuous free radical polymerization reactor

1992 ◽  
Vol 16 (8) ◽  
pp. 777-791 ◽  
Author(s):  
M. van Dootingh ◽  
F. Viel ◽  
D. Rakotopara ◽  
J.P. Gauthier ◽  
P. Hobbes
Keyword(s):  
Free Radical ◽  
State Estimation ◽  
Radical Polymerization ◽  
Free Radical Polymerization ◽  
Polymerization Reactor

scholarly journals Decompositions in the production of low density polyethylene: Reasons, consequences and prevention

2007 ◽  
Vol 61 (6) ◽  
pp. 357-363 ◽  
Author(s):  
Dragoslav Stoiljkovic ◽  
Slobodan Jovanovic ◽  
Jovica Djordjevic ◽  
Budimir Damjanovic
Keyword(s):  
High Pressure ◽  
Free Radical ◽  
Radical Polymerization ◽  
Scientific Literature ◽  
Free Radical Polymerization ◽  
Low Density Polyethylene ◽  
Low Density ◽  
Industrial Practice ◽  
Polymerization Reactor

In the production of low density polyethylene by free radical polymerization of ethylene at high pressure, ethylene and polyethylene occasionally decompose to carbon, hydrogen and methane resulting in an enormous increase of pressure and temperature. Huge explosions occur in a polymerization reactor and in other parts of the installation. In addition to the well known reasons of decompositions, in this work it is pointed out that the polymerization under critical entropy conditions is an additional cause of explosions, which has not been recognized and elaborated in scientific literature and industrial practice.

Non-isothermal Kinetics of Free Radical Polymerization of 2-Phenylethyl (Meth)acrylate

2018 ◽  
Vol 8 (3) ◽  
pp. 585-594
Author(s):  
Khdbudin Mulani ◽  
Ravindra Ghorpade ◽  
Surendra Ponrathnam ◽  
Nayaku Chavan ◽  
Kamini Donde
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Free Radical Polymerization ◽  
Isothermal Kinetics ◽  
Kinetics Of

Oxygen-Initiated Free-Radical Polymerization of Alkyl Acrylates at High Temperatures

2021 ◽  
Author(s):  
Shi Liu ◽  
Lauren Chua ◽  
Ahmad Arabi Shamsabadi ◽  
Patrick Corcoran ◽  
Abhirup Patra ◽  
...  
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
High Temperatures ◽  
Free Radical Polymerization ◽  
Alkyl Acrylates
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