Simulation and Optimization of Polymerization Reactor for the Production of Polyethylene Terephthalate (PET)

The sole objective of this paper is to investigate Simulation and Optimization process for the production of polyethylene terephthalate, the biggest polymer being consumed all over the world. In this way, two polymerization reactors are replaced with one polymerization reactor. In this way equipment and operating and many other cost was reduced. Discussion has also been made on the optimum temperature and pressure along with most suitable catalyst. The objective function for the polymerization reactor is to maximize the production as well as conversion. It is found that the reactor should be operated at a high temperature initially to obtain high conversion of Dimethyl Terephthalate (DMT) first, but then it should be lowered to reduce the formation of side products. Previous work was done on Simulation for the batch reactor only but in this work the Simulation was applied to the continuous polymerization reactor and results is investigated.

Structure, processing and performance of ultra-high molecular weight polyethylene (IUPAC Technical Report). Part 2: crystallinity and supra molecular structure

Test methods including OM, SEM, TEM, DSC, SAXS, WAXS, and IR were used to characterise supra-molecular structure in three batches of polyethylene (PE), which had weight-average relative molar masses ${\overline{M}}_{\text{w}}$of approximately 0.6 × 106, 5 × 106, and 9 × 106. They were applied to compression mouldings made by the polymer manufacturer. Electron microscopy showed that powders formed in the polymerization reactor consisted of irregularly shaped grains between 50 and 250 μm in diameter. Higher magnification revealed that each grain was an aggregate, composed of particles between 0.4 and 0.8 μm in diameter, which were connected by long, thin fibrils. In compression mouldings, lamellar thicknesses ranged from 7 to 23 nm. Crystallinity varied between 70 and 75 % in reactor powder, but was lower in compression mouldings. Melting peak temperatures ranged from 138 to 145 °C, depending on processing history. DMTA showed that the glass transition temperature θg was −120 °C for all three grades of polyethylene. IR spectroscopy found negligibly small levels of oxidation and thermal degradation in mouldings. Optical microscopy revealed the presence of visible fusion defects at grain boundaries. It is concluded that relatively weak defects can be characterized using optical microscopy, but there is a need for improved methods that can detect less obvious fusion defects.