The thermoluminescence of single crystals of ammonium perchlorate irradiated with X rays, uv light, or high energy electrons has been measured between 80 and 420 K. With a heating rate of 5 K/min. prominent peaks occur at 95, 113, 134, 246, and 320 K; an additional peak is found at 347 K after longer irradiation times. The absorption spectrum of uv-irradiated ammonium perchlorate has also been measured and shows bands at 300, 360, and 610 nm. A comparison of these data with chemical and spectroscopic evidence obtained by other workers has permitted the probable identification of ClO3−, ClO−, ClO2, and F centres as radiation products. Three thermoluminescent peaks remain unassigned.
