31P and 15N solid-state nuclear magnetic resonance spectroscopic study of some monophospha-λ5-azenes

1994 ◽  
Vol 3 (6) ◽  
pp. 353-356
Author(s):  
W. Domalewski ◽  
L. Stefaniak ◽  
M.J. Potrzebowski ◽  
G.A. Webb
1984 ◽  
Vol 62 (3) ◽  
pp. 621-627 ◽  
Author(s):  
Tim Allman ◽  
Ram G. Goel

Cationic complexes of the type [Hg(phosphine)n](ClO4)2 (n = 2, 3, 4) (phosphine = P(t-Bu)3, PCy3, P(4-Me2NC6H4)3, P(4-MeOC6H4)3, P(4-MeC6H4)3, P(3-MeC6H4)3, P(2-MeC6H4)3, P(4-FC6H4)3, P(4-ClC6H4)3) have been prepared and studied by vibrational spectroscopy in the perchlorate and low frequency regions, as well as by 31P and 199Hg nmr. The skeletal Hg—P frequencies have been assigned in both solution and the solid state. It was found that 1J(Hg—P) decreases with increasing phosphine basicity and that it is also dependent upon sample concentration and temperature.


2021 ◽  
Vol 126 (14) ◽  
Author(s):  
Deniz Aybas ◽  
Janos Adam ◽  
Emmy Blumenthal ◽  
Alexander V. Gramolin ◽  
Dorian Johnson ◽  
...  

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