Evaluation of Heavy-Metal Contamination in Groundwater using Hydrogeochemical and Multivariate statistical Analyses

Author(s):  
Sang Yong Chung ◽  
R. Rajesh ◽  
S. Venkatramanan
1985 ◽  
Vol 63 (3) ◽  
pp. 448-455 ◽  
Author(s):  
Anders Nordgren ◽  
Erland Bååth ◽  
Bengt Söderström

The microfungal species composition was studied in coniferous forest soils surrounding a brass mill at Gusum in southeast Sweden. Both the Cu and Zn concentrations were ca. 20 000 μg/g dry soil close to the mill. Pb concentration was ca. 1000 μg/g dry soil and the pH about 2 units above the normal of 3.5–4. The microfungal species composition (determined by the dilution plate technique) was strongly affected by the heavy-metal contamination. Close to the mill there was a decrease in isolation frequency of fungi common in coniferous forest soils, e.g., Penicillium spinulosum, P. montanense, P. brevicompactum, Oidiodendron cf. tenuissimum, O. cf. echinulatum, and O. maius. Other less common or rare fungi increased, e.g., Paecilomyces farinosus, Geomyces pannorum, Chalara constricta, C. longipes, and sterile forms. Fungi of the genus Mortierella seemed affected little by the heavy-metal contamination. Multivariate statistical analyses showed that the heavy-metal pollution was the dominating influence along the metal gradient and that soil moisture and loss on ignition accounted for little of the variation in the fungal data.


2021 ◽  
Vol 11 (8) ◽  
pp. 3646
Author(s):  
Francesco Caridi ◽  
Giuseppe Acri ◽  
Alberto Belvedere ◽  
Vincenza Crupi ◽  
Maurizio D’Agostino ◽  
...  

Flour investigation, in terms of physical and chemical pollutants and mineral content, is of great interest, in view of its high consumption for nutritional purposes. In this study, eleven types of flour (five samples for each one), coming from large retailers and employed by people for different cooking food purposes, were investigated through high-purity germanium (HPGe) gamma spectrometry, in order to estimate natural (40K) and anthropogenic (137Cs) radioisotope specific activity and thus, to assess the radiological risk due to the flour ingestion. Inductively-coupled plasma mass spectrometry (ICP-MS) and inductively-coupled plasma emission spectroscopy (ICP-OES) were also employed to evaluate any possible heavy metal contamination and the mineral composition, and to perform multivariate statistical analysis to deduce the flour authenticity. The evaluation of dose levels due to flour ingestion was performed, for the age category higher than 17 years, taking into account the average yearly consumption in Italy and assuming this need to be satisfied from a single type of flour as a precaution. All obtained results are under the allowable level set by Italian legislation (1 mSv y−1), thus excluding the risk of ionizing radiation effects on humans. As far as heavy metal contamination is concerned, Cd and Pb concentrations turned out to be lower than the threshold values, thus excluding their presence as pollutants. Finally, the multivariate statistical analysis allowed to unambiguously correlate flour samples to their botanical origin, according to their elemental concentrations.


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