Characterization of a blue-copper protein, auracyanin, of the filamentous anoxygenic phototrophic bacterium Roseiflexus castenholzii

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We report the synthesis, spectroscopic characterization and X-ray crystal structures of CuI/II complexes prepared from the N2S2 macrocycle 1,8-dithia-4,11-diazacyclotetradecane.


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