Evaluating porous media wettability from changes in Helmholtz free energy using spontaneous imbibition profiles

2021 ◽  
pp. 104038
Author(s):  
Amin Alinejad ◽  
Hassan Dehghanpour
1983 ◽  
Vol 48 (10) ◽  
pp. 2888-2892 ◽  
Author(s):  
Vilém Kodýtek

A special free energy function is defined for a solution in the osmotic equilibrium with pure solvent. The partition function of the solution is derived at the McMillan-Mayer level and it is related to this special function in the same manner as the common partition function of the system to its Helmholtz free energy.


Metals ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 195
Author(s):  
Pavel A. Korzhavyi ◽  
Jing Zhang

A simple modeling method to extend first-principles electronic structure calculations to finite temperatures is presented. The method is applicable to crystalline solids exhibiting complex thermal disorder and employs quasi-harmonic models to represent the vibrational and magnetic free energy contributions. The main outcome is the Helmholtz free energy, calculated as a function of volume and temperature, from which the other related thermophysical properties (such as temperature-dependent lattice and elastic constants) can be derived. Our test calculations for Fe, Ni, Ti, and W metals in the paramagnetic state at temperatures of up to 1600 K show that the predictive capability of the quasi-harmonic modeling approach is mainly limited by the electron density functional approximation used and, in the second place, by the neglect of higher-order anharmonic effects. The developed methodology is equally applicable to disordered alloys and ordered compounds and can therefore be useful in modeling realistically complex materials.


1999 ◽  
Vol 09 (03) ◽  
pp. 175-186 ◽  
Author(s):  
HAROLD SZU

Unified Lyaponov function is given for the first time to prove the learning methodologies convergence of artificial neural network (ANN), both supervised and unsupervised, from the viewpoint of the minimization of the Helmholtz free energy at the constant temperature. Early in 1982, Hopfield has proven the supervised learning by the energy minimization principle. Recently in 1996, Bell & Sejnowski has algorithmically demonstrated. Independent Component Analyses (ICA) generalizing the Principal Component Analyses (PCA) that the continuing reduction of early vision redundancy happens towards the "sparse edge maps" by maximization of the ANN output entropy. We explore the combination of both as Lyaponov function of which the proven convergence gives both learning methodologies. The unification is possible because of the thermodynamics Helmholtz free energy at a constant temperature. The blind de-mixing condition for more than two objects using two sensor measurement. We design two smart cameras with short term working memory to do better image de-mixing of more than two objects. We consider channel communication application that we can efficiently mix four images using matrices [AO] and [Al] to send through two channels.


SPE Journal ◽  
2018 ◽  
Vol 24 (01) ◽  
pp. 158-177 ◽  
Author(s):  
Pål Østebø Andersen ◽  
Yangyang Qiao ◽  
Dag Chun Standnes ◽  
Steinar Evje

Summary This paper presents a numerical study of water displacing oil using combined cocurrent/countercurrent spontaneous imbibition (SI) of water displacing oil from a water-wet matrix block exposed to water on one side and oil on the other. Countercurrent flows can induce a stronger viscous coupling than during cocurrent flows, leading to deceleration of the phases. Even as water displaces oil cocurrently, the saturation gradient in the block induces countercurrent capillary diffusion. The extent of countercurrent flow may dominate the domain of the matrix block near the water-exposed surfaces while cocurrent imbibition may dominate the domain near the oil-exposed surfaces, implying that one unique effective relative permeability curve for each phase does not adequately represent the system. Because relative permeabilities are routinely measured cocurrently, it is an open question whether the imbibition rates in the reservoir (depending on a variety of flow regimes and parameters) will in fact be correctly predicted. We present a generalized model of two-phase flow dependent on momentum equations from mixture theory that can account dynamically for viscous coupling between the phases and the porous media because of fluid/rock interaction (friction) and fluid/fluid interaction (drag). These momentum equations effectively replace and generalize Darcy's law. The model is parameterized using experimental data from the literature. We consider a water-wet matrix block in one dimension that is exposed to oil on one side and water on the other side. This setup favors cocurrent SI. We also account for the fact that oil produced countercurrently into water must overcome the so-called capillary backpressure, which represents a resistance for oil to be produced as droplets. This parameter can thus influence the extent of countercurrent production and hence viscous coupling. This complex mixture of flow regimes implies that it is not straightforward to model the system by a single set of relative permeabilities, but rather relies on a generalized momentum-equation model that couples the two phases. In particular, directly applying cocurrently measured relative permeability curves gives significantly different predictions than the generalized model. It is seen that at high water/oil-mobility ratios, viscous coupling can lower the imbibition rate and shift the production from less countercurrent to more cocurrent compared with conventional modeling. Although the viscous-coupling effects are triggered by countercurrent flow, reducing or eliminating countercurrent production by means of the capillary backpressure does not eliminate the effects of viscous coupling that take place inside the core, which effectively lower the mobility of the system. It was further seen that viscous coupling can increase the remaining oil saturation in standard cocurrent-imbibition setups.


Author(s):  
Markus Schmuck ◽  
Marc Pradas ◽  
Grigorios A. Pavliotis ◽  
Serafim Kalliadasis

We derive a new, effective macroscopic Cahn–Hilliard equation whose homogeneous free energy is represented by fourth-order polynomials, which form the frequently applied double-well potential. This upscaling is done for perforated/strongly heterogeneous domains. To the best knowledge of the authors, this seems to be the first attempt of upscaling the Cahn–Hilliard equation in such domains. The new homogenized equation should have a broad range of applicability owing to the well-known versatility of phase-field models. The additionally introduced feature of systematically and reliably accounting for confined geometries by homogenization allows for new modelling and numerical perspectives in both science and engineering. Our results are applied to wetting dynamics in porous media and to a single channel with strongly heterogeneous walls.


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