Ceria added Sb-V2O5/TiO2 catalysts for low temperature NH3 SCR: Physico-chemical properties and catalytic activity

2013 ◽  
Vol 142-143 ◽  
pp. 705-717 ◽  
Author(s):  
Kyung Ju Lee ◽  
Pullur Anil Kumar ◽  
Muhammad Salman Maqbool ◽  
Komateedi Narayana Rao ◽  
Kwang Ho Song ◽  
...  
2018 ◽  
Vol 284 ◽  
pp. 839-844 ◽  
Author(s):  
V.A. Lebedev ◽  
Andrey A. Shoppert

Modern aluminum electrolysis in cryolite-alumina melts is energy-intensive, inefficient and environmentally hazardous production. Addressing these significant shortcomings, the technology of low-temperature electrolyte is directed. The basis of low-temperature electrolysis is potassium cryolite, which results in high magnitude and rate of dissolution of alumina. Additive of sodium and lithium fluorides provide the necessary conductivity. Experimental investigation of these properties is extremely time consuming. In this work, as a parameter, which will allow to characterize effectively and rapidly the complexing ability of cryolite melts, the ratio of cationic ion power of Al3+ to the total power of the other cations of the melt is proposed. Regression analyses of the known experimental data establish the existence with a high level of reliability (R2=0.966-0.995) of a directly proportional dependence of this parameter on solubility of alumina and electrical conductivity of cryolite melts.


Energies ◽  
2020 ◽  
Vol 13 (24) ◽  
pp. 6564
Author(s):  
Krzysztof Górski ◽  
Ruslans Smigins ◽  
Rafał Longwic

Physico-chemical properties of diethyl ether/linseed oil (DEE/LO) fuel blends were empirically tested in this article for the first time. In particular, kinematic viscosity (ν), density (ρ), lower heating value (LHV), cold filter plugging point (CFPP) and surface tension (σ) were examined. For this research diethyl ether (DEE) was blended with linseed oil (LO) in volumetric ratios of 10%, 20% and 30%. Obtained results were compared with literature data of diethyl ether/rapeseed oil (DEE/RO) fuel blends get in previous research in such a way looking on differences also between oil types. It was found that DEE impacts significantly on the reduction of plant oil viscosity, density and surface tension and improve low temperature properties of tested oils. In particular, the addition of 10% DEE to LO effectively reduces its kinematic viscosity by 53% and even by 82% for the blend containing 30% DEE. Tested ether reduces density and surface tension of LO up to 6% and 25% respectively for the blends containing 30% DEE. The measurements of the CFPP showed that DEE significantly improves the low temperature properties of LO. In the case of the blend containing 30% DEE the CFPP can be lowered up to −24 °C. For this reason DEE/LO blends seem to be valuable as a fuel for diesel engines in the coldest season of the year. Moreover, DEE/LO blends have been tested in the engine research. Based on results it can be stated that the engine operated with LO results in worse performance compared with regular diesel fuel (DF). However, it was found that these disadvantages could be reduced with DEE as a component of the fuel mixture. Addition of this ether to LO improves the quality of obtained fuel blends. For this reason, the efficiency of DEE/LO blend combustion process is similar for the engine fuelled with regular diesel fuel. In this research it was confirmed that the smoke opacity reaches the highest value for the engine fuelled with plant oils. However, addition of 20% DEE reduces this emission to the value comparable for the engine operated with diesel fuel.


2014 ◽  
Vol 16 (7) ◽  
pp. 3463-3471 ◽  
Author(s):  
Karolina Matuszek ◽  
Anna Chrobok ◽  
Fergal Coleman ◽  
Kenneth R. Seddon ◽  
Małgorzata Swadźba-Kwaśny

The speciation of a family of inexpensive, easily prepared protonic ionic liquids, their physico-chemical properties and their performance as catalysts in the model esterification reaction have been correlated.


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