Improved one-pot synthesis of furfural from corn stalk with heterogeneous catalysis using corn stalk as biobased carrier in deep eutectic solvent-water system

2021 ◽  
pp. 125691
Author(s):  
Li Ji ◽  
Zhengyu Tang ◽  
Dong Yang ◽  
Cuiluan Ma ◽  
Yu-Cai He
Keyword(s):  
Heterogeneous Catalysis ◽  
Deep Eutectic Solvent ◽  
Water System ◽  
Corn Stalk ◽  
One Pot ◽  
Solvent Water ◽  
One Pot Synthesis

scholarly journals Chemoenzymatic Conversion of Biomass-Derived D-Xylose to Furfuryl Alcohol with Corn Stalk-Based Solid Acid Catalyst and Reductase Biocatalyst in a Deep Eutectic Solvent–Water System

Processes ◽  
2022 ◽  
Vol 10 (1) ◽  
pp. 113
Author(s):  
Jianguang Liang ◽  
Li Ji ◽  
Jiarui He ◽  
Shuxin Tang ◽  
Yucai He
Keyword(s):  
Furfuryl Alcohol ◽  
Solid Acid ◽  
Solid Acid Catalyst ◽  
Deep Eutectic Solvent ◽  
Water System ◽  
Value Added ◽  
Acid Catalyst ◽  
Corn Stalk ◽  
Solvent Water ◽  
Water Media

In this work, the feasibility of chemoenzymatically transforming biomass-derived D-xylose to furfuryl alcohol was demonstrated in a tandem reaction with SO42−/SnO2-CS chemocatalyst and reductase biocatalyst in the deep eutectic solvent (DES)–water media. The high furfural yield (44.6%) was obtained by catalyzing biomass-derived D-xylose (75.0 g/L) in 20 min at 185 °C with SO42−/SnO2-CS (1.2 wt%) in DES ChCl:EG–water (5:95, v/v). Subsequently, recombinant E.coli CF cells harboring reductases transformed D-xylose-derived furfural (200.0 mM) to furfuryl alcohol in the yield of 35.7% (based on D-xylose) at 35 °C and pH 7.5 using HCOONa as cosubstrate in ChCl:EG–water. This chemoenzymatic cascade catalysis strategy could be employed for the sustainable production of value-added furan-based chemical from renewable bioresource.

Deep eutectic solvent mediated rapid and selective one-pot synthesis of 5-alkylidene-Thiazolones

2021 ◽  
Vol 22 ◽  
pp. 100457
Author(s):  
Najmedin Azizi ◽  
Mahnaz Qomi ◽  
Malihe Asghari ◽  
Elham Farhadi
Keyword(s):  
Deep Eutectic Solvent ◽  
One Pot ◽  
One Pot Synthesis

ChemInform Abstract: One-Pot Synthesis of Polysubstituted Imidazoles in a Broensted Acidic Deep Eutectic Solvent.

ChemInform ◽  
2013 ◽  
Vol 44 (39) ◽  
pp. no-no
Author(s):  
Liang Wang ◽  
Xia Zhong ◽  
Min Zhou ◽  
Wei-you Zhou ◽  
Qun Chen ◽  
...  
Keyword(s):  
Deep Eutectic Solvent ◽  
One Pot ◽  
One Pot Synthesis

An Efficient Benzoxaborole One‐Pot Synthesis by Silia Cat DPP‐Pd Heterogeneous Catalysis using Diboronic Acid

2018 ◽  
Vol 360 (14) ◽  
pp. 2757-2761 ◽  
Author(s):  
Kana Kunihiro ◽  
Laurence Dumais ◽  
Guillaume Lafitte ◽  
Emeric Varvier ◽  
Loïc Tomas ◽  
...  
Keyword(s):  
Heterogeneous Catalysis ◽  
One Pot ◽  
One Pot Synthesis

Collective use of deep eutectic solvent for one-pot synthesis of ternary Sn/SnO2@C electrode for supercapacitor

2018 ◽  
Vol 732 ◽  
pp. 694-704 ◽  
Author(s):  
Gaurav M. Thorat ◽  
Harsharaj S. Jadhav ◽  
Wook-Jin Chung ◽  
Jeong Gil Seo
Keyword(s):  
Deep Eutectic Solvent ◽  
One Pot ◽  
One Pot Synthesis

One-Pot Synthesis of Nitriles from Aldehydes Catalyzed by Deep Eutectic Solvent

Synthesis ◽  
2013 ◽  
Vol 45 (23) ◽  
pp. 3295-3299 ◽  
Author(s):  
Jayashree Nagarkar ◽  
Umakant Patil ◽  
Suresh Shendage
Keyword(s):  
Deep Eutectic Solvent ◽  
One Pot ◽  
One Pot Synthesis

scholarly journals Deep eutectic solvent as solvent and catalyst: one-pot synthesis of 1,3-dinitropropanes via tandem Henry reaction/Michael addition

2020 ◽  
Vol 18 (41) ◽  
pp. 8395-8401
Author(s):  
Greta Colombo Dugoni ◽  
Alessandro Sacchetti ◽  
Andrea Mele
Keyword(s):  
Michael Addition ◽  
Deep Eutectic Solvent ◽  
Aromatic Aldehydes ◽  
Henry Reaction ◽  
One Pot ◽  
One Pot Synthesis ◽  
Mw Irradiation

1,3-Dinitropropane derivatives were obtained in a simple one-pot procedure from nitromethane and aromatic aldehydes by combining MW irradiation and the use of DES as both catalyst and solvent.

Molar Enthalpy of Mixing for Choline Chloride/Urea Deep Eutectic Solvent + Water System

2016 ◽  
Vol 61 (12) ◽  
pp. 4172-4177 ◽  
Author(s):  
Chunyan Ma ◽  
Yanhua Guo ◽  
Dongxue Li ◽  
Jianpeng Zong ◽  
Xiaoyan Ji ◽  
...  
Keyword(s):  
Choline Chloride ◽  
Deep Eutectic Solvent ◽  
Water System ◽  
Enthalpy Of Mixing ◽  
Molar Enthalpy ◽  
Solvent Water
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