Chemoenzymatic Conversion of Biomass-Derived D-Xylose to Furfuryl Alcohol with Corn Stalk-Based Solid Acid Catalyst and Reductase Biocatalyst in a Deep Eutectic Solvent–Water System

In this work, the feasibility of chemoenzymatically transforming biomass-derived D-xylose to furfuryl alcohol was demonstrated in a tandem reaction with SO42−/SnO2-CS chemocatalyst and reductase biocatalyst in the deep eutectic solvent (DES)–water media. The high furfural yield (44.6%) was obtained by catalyzing biomass-derived D-xylose (75.0 g/L) in 20 min at 185 °C with SO42−/SnO2-CS (1.2 wt%) in DES ChCl:EG–water (5:95, v/v). Subsequently, recombinant E.coli CF cells harboring reductases transformed D-xylose-derived furfural (200.0 mM) to furfuryl alcohol in the yield of 35.7% (based on D-xylose) at 35 °C and pH 7.5 using HCOONa as cosubstrate in ChCl:EG–water. This chemoenzymatic cascade catalysis strategy could be employed for the sustainable production of value-added furan-based chemical from renewable bioresource.

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Organic Solid Acid Catalyst for Efficient Conversion of Furfuryl Alcohol to Biofuels

ChemistrySelect ◽

10.1002/slct.201601285 ◽

2016 ◽

Vol 1 (19) ◽

pp. 6079-6085 ◽

Cited By ~ 5

Author(s):

Md. Mominul Islam ◽

Subhajit Bhunia ◽

Rostam Ali Molla ◽

Asim Bhaumik ◽

Sk. Manirul Islam

Keyword(s):

Furfuryl Alcohol ◽

Solid Acid ◽

Solid Acid Catalyst ◽

Acid Catalyst ◽

Efficient Conversion ◽

Organic Solid

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Hydrothermal carbon enriched with sulfonic and carboxyl groups as an efficient solid acid catalyst for butanolysis of furfuryl alcohol

Catalysis Communications ◽

10.1016/j.catcom.2019.02.016 ◽

2019 ◽

Vol 123 ◽

pp. 109-113 ◽

Cited By ~ 4

Author(s):

Jinfan Yang ◽

Hongyu Zhang ◽

Zhifeng Ao ◽

Sufeng Zhang

Keyword(s):

Furfuryl Alcohol ◽

Solid Acid ◽

Solid Acid Catalyst ◽

Acid Catalyst ◽

Carboxyl Groups

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Enhanced enzymatic hydrolysis of poplar cellulosic residue fractionated by a magnetic carbon-based solid-acid catalyst in the γ-valerolactone–water system

Industrial Crops and Products ◽

10.1016/j.indcrop.2021.114397 ◽

2022 ◽

Vol 176 ◽

pp. 114397

Author(s):

Qiong Wang ◽

Yunyun Liu ◽

Yi Zhang ◽

Yang Chen ◽

Qifa Feng ◽

...

Keyword(s):

Enzymatic Hydrolysis ◽

Solid Acid ◽

Solid Acid Catalyst ◽

Water System ◽

Acid Catalyst ◽

Magnetic Carbon ◽

Hydrolysis Of ◽

Carbon Based

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Improved one-pot synthesis of furfural from corn stalk with heterogeneous catalysis using corn stalk as biobased carrier in deep eutectic solvent-water system

Bioresource Technology ◽

10.1016/j.biortech.2021.125691 ◽

2021 ◽

pp. 125691

Author(s):

Li Ji ◽

Zhengyu Tang ◽

Dong Yang ◽

Cuiluan Ma ◽

Yu-Cai He

Keyword(s):

Heterogeneous Catalysis ◽

Deep Eutectic Solvent ◽

Water System ◽

Corn Stalk ◽

One Pot ◽

Solvent Water ◽

One Pot Synthesis

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Efficient Conversion of Furfuryl Alcohol into Alkyl Levulinates Catalyzed by an Organic-Inorganic Hybrid Solid Acid Catalyst

ChemSusChem ◽

10.1002/cssc.201000231 ◽

2011 ◽

Vol 4 (1) ◽

pp. 112-118 ◽

Cited By ~ 130

Author(s):

Zehui Zhang ◽

Kun Dong ◽

Zongbao Kent Zhao

Keyword(s):

Furfuryl Alcohol ◽

Solid Acid ◽

Solid Acid Catalyst ◽

Acid Catalyst ◽

Inorganic Hybrid ◽

Efficient Conversion ◽

Alkyl Levulinates

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Catalytic conversion of xylose and corn stalk into furfural over carbon solid acid catalyst in γ-valerolactone

Bioresource Technology ◽

10.1016/j.biortech.2016.02.108 ◽

2016 ◽

Vol 209 ◽

pp. 108-114 ◽

Cited By ~ 71

Author(s):

Tingwei Zhang ◽

Wenzhi Li ◽

Zhiping Xu ◽

Qiyu Liu ◽

Qiaozhi Ma ◽

...

Keyword(s):

Solid Acid ◽

Solid Acid Catalyst ◽

Acid Catalyst ◽

Catalytic Conversion ◽

Corn Stalk

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Exploration of benign deep eutectic solvent–water system for the high-efficient production of furfurylamine from sugarcane bagasse via chemoenzymatic cascade catalysis

Green Chemistry ◽

10.1039/d1gc03010h ◽

2021 ◽

Author(s):

Qing Li ◽

Junhua Di ◽

Xiaolong Liao ◽

Jiacheng Ni ◽

Qi Li ◽

...

Keyword(s):

Sugarcane Bagasse ◽

Deep Eutectic Solvent ◽

Reaction System ◽

Water System ◽

Value Added ◽

Environmentally Friendly ◽

Cost Effective ◽

Efficient Production ◽

Solvent Water ◽

High Efficient

Recently, cost-effective production of highly value-added furan chemicals from abundant and renewable bioresources has gained much attentions via chemoenzymatic approach in environmentally-friendly reaction system. In this work, chemoenzymatic cascade reaction...

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