The role of oxygen and hydroxyl support species on the mechanism of H2 production in the steam reforming of phenol over metal oxide-supported-Rh and -Fe catalysts

2006 ◽  
Vol 112 (1-4) ◽  
pp. 89-93 ◽  
Author(s):  
K. Polychronopoulou ◽  
C.N. Costa ◽  
A.M. Efstathiou
2017 ◽  
Vol 19 (6) ◽  
pp. 4199-4207 ◽  
Author(s):  
Catherine K. S. Choong ◽  
Luwei Chen ◽  
Yonghua Du ◽  
Martin Schreyer ◽  
S. W. Daniel Ong ◽  
...  

Effect of metal–support interaction on the generation of Rh–FexOy active sites is investigated via various in situ techniques.


2013 ◽  
Vol 56 (18-20) ◽  
pp. 1672-1685 ◽  
Author(s):  
M. C. Sanchez-Sanchez ◽  
R. M. Navarro ◽  
I. Espartero ◽  
A. A. Ismail ◽  
S. A. Al-Sayari ◽  
...  

2010 ◽  
Vol 132 ◽  
pp. 205-219 ◽  
Author(s):  
Raul Pérez-Hernández ◽  
A. Gutiérrez-Martínez ◽  
Alvaro Mayoral ◽  
F. Leonard Deepak ◽  
Ma. E. Fernández-García ◽  
...  

One dimensional (1-D) and three dimensional (3-D) ZnO were growth by a hydrothermal method. ZnO 1-D was employed as a support for silver nanoparticles in order to design a new catalyst and used on the steam reforming of methanol (SRM) reaction for H2 production. The catalytic activity of the Ag/ZnO sample with low content of Ag showed better performance on the SRM reaction than on high silver loading catalyst. So, the sample with small Ag particle size showed best performance in methanol conversion than catalyst with big Ag particle size, this finding could be attributed to the high ZnO/Ag ratio. According to results of SEM and TEM techniques the catalytic activity: methanol conversion, H2 and low CO production observed on the Ag/ZnO 1-D catalyst occurs in the edge sites rather than the rim sites. The role of Ag is to accept the hydrogen to be released to the gas phase. In addition, the 1.5Ag/ZnO 1-D catalyst showed good stability during the reaction.


2010 ◽  
Vol 122 (50) ◽  
pp. 9874-9878 ◽  
Author(s):  
Gong Zhou ◽  
Laura Barrio ◽  
Stefano Agnoli ◽  
Sanjaya D. Senanayake ◽  
Jaime Evans ◽  
...  

Author(s):  
Lars Mohrhusen ◽  
Jessica Kräuter ◽  
Katharina Al-Shamery

The photochemical conversion of organic compounds on tailored transition metal oxide surfaces by (UV) irradiation has found wide applications ranging from the production of chemicals to the degradation of organic...


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