In-situ monitoring of transition metal complex adsorption on oxide surfaces during the first stages of supported metal catalyst preparation

2014 ◽  
Vol 235 ◽  
pp. 245-249 ◽  
Author(s):  
Juliette Blanchard ◽  
Antoine Hervier ◽  
Guylène Costentin ◽  
John Regalbuto ◽  
Catherine Louis ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complex ◽  
Transition Metal Complex ◽  
Catalyst Preparation ◽  
In Situ Monitoring ◽  
Metal Catalyst ◽  
Oxide Surfaces ◽  
Supported Metal Catalyst ◽  
Complex Adsorption

The genesis of a heterogeneous catalyst: in situ observation of a transition metal complex adsorbing onto an oxide surface in solution

2014 ◽  
Vol 50 (19) ◽  
pp. 2409-2411 ◽  
Author(s):  
Antoine Hervier ◽  
Juliette Blanchard ◽  
Guylène Costentin ◽  
John Regalbuto ◽  
Catherine Louis ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complex ◽  
Quartz Crystal ◽  
Transition Metal Complex ◽  
Oxide Surface ◽  
In Situ Observation ◽  
Complex Adsorption ◽  
Solid Liquid Interface ◽  
Solid Liquid

Transition metal complex adsorption onto an oxide surface was observed in situ using a quartz crystal microbalance at the solid–liquid interface.

Unsymmetrical 1,1-diborated multisubstituted sp3-carbons formed via a metal-free concerted-asynchronous mechanism

2015 ◽  
Vol 13 (37) ◽  
pp. 9659-9664 ◽  
Author(s):  
Ana B. Cuenca ◽  
Jessica Cid ◽  
Diego García-López ◽  
Jorge J. Carbó ◽  
Elena Fernández
Keyword(s):  
Transition Metal ◽  
Metal Complex ◽  
Transition Metal Complex ◽  
Diazo Compounds ◽  
Cyclic Ketones ◽  
Metal Free

We have experimentally proved and computationally rationalized the unsymmetrical 1,1-diboration of diazo compounds, formed in situ from aldehydes and cyclic and non-cyclic ketones, in the absence of any transition metal complex.

A transition metal complex containing pyrazine-2,5-dicarboxylato bridging ligands: a novel three-dimensional manganese(II) compound

2003 ◽  
Vol 6 (9) ◽  
pp. 1224-1227 ◽  
Author(s):  
Garikoitz Beobide ◽  
Oscar Castillo ◽  
Antonio Luque ◽  
Urko Garcı́a-Couceiro ◽  
Juan P. Garcı́a-Teran ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complex ◽  
Transition Metal Complex ◽  
Three Dimensional ◽  
Bridging Ligands
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