Corrigendum to “Noncovalent bonding: Stacking interactions of chelate rings of transition metal complexes” [Coord. Chem. Rev. 345 (2017) 318–341]

2018 ◽  
Vol 376 ◽  
pp. 590
Author(s):  
Dušan P. Malenov ◽  
Goran V. Janjić ◽  
Vesna B. Medaković ◽  
Michael B. Hall ◽  
Snežana D. Zarić
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Stacking Interactions ◽  
Noncovalent Bonding ◽  
Chelate Rings

Noncovalent bonding: Stacking interactions of chelate rings of transition metal complexes

2017 ◽  
Vol 345 ◽  
pp. 318-341 ◽  
Author(s):  
Dušan P. Malenov ◽  
Goran V. Janjić ◽  
Vesna B. Medaković ◽  
Michael B. Hall ◽  
Snežana D. Zarić
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Stacking Interactions ◽  
Noncovalent Bonding ◽  
Chelate Rings

Parallel stacking interactions in square-planar transition-metal complexes containing fused chelate and C6-aromatic rings

2012 ◽  
Vol 68 (3) ◽  
pp. 261-265 ◽  
Author(s):  
Dušan N. Sredojević ◽  
Dubravka Z. Vojislavljević ◽  
Zoran D. Tomić ◽  
Snežana D. Zarić
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Large Fraction ◽  
Stacking Interactions ◽  
Aromatic Rings ◽  
Metal Type ◽  
Square Planar ◽  
Planar Transition ◽  
Chelate Rings

Stacking interactions in the crystal structures of square-planar transition metal complexes from the Cambridge Structural Database with five- and six-membered chelate rings fused with C6-arom rings (arom = aromatic) were analyzed. The distribution of distances between the closest C6-arom–C6-arom and C6-arom–chelate contacts shows that in a large fraction of the intermolecular interactions the C6-arom ring of one molecule is closer to the chelate than to the C6-arom ring of the other molecule. These results indicate a possible preference of the C6-arom ring to form stacking contacts with the chelate rings. The preference is ubiquitous and does not depend on the metal type.

Stacking interactions of the methylated cyclopentadienyl ligands in the crystal structures of transition metal complexes

2020 ◽  
Vol 76 (2) ◽  
pp. 252-258 ◽  
Author(s):  
Dušan P. Malenov ◽  
Jelena P. Blagojević Filipović ◽  
Snežana D. Zarić
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Crystal Structures ◽  
Transition Metal Complexes ◽  
Electrostatic Potential ◽  
Stacking Interactions ◽  
Cyclopentadienyl Ligands ◽  
Π Interactions ◽  
Structural Database ◽  
Oppositely Charged

In the crystal structures of methylated cyclopentadienyl (Cp) complexes (MeCp, Me4Cp and Me5Cp) deposited in the Cambridge Structural Database, certain orientation types of stacked contacts can be noted as the most frequent. These orientation preferences can be well explained by the matching of oppositely charged regions of electrostatic potential. Parallel displaced stacking, large offset stacking and C—H...π interactions are the dominant interaction types that are responsible for the arrangement in the crystal structures of stacked methylated Cp complexes.

Strong stacking interactions at large horizontal displacements of tropylium and cyclooctatetraenide ligands of transition metal complexes: crystallographic and DFT study

CrystEngComm ◽  
2020 ◽  
Vol 22 (22) ◽  
pp. 3831-3839 ◽  
Author(s):  
Dušan P. Malenov ◽  
Snežana D. Zarić
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Crystal Structures ◽  
Transition Metal Complexes ◽  
Dft Study ◽  
Stacking Interactions ◽  
Horizontal Displacements

Large offset stacking of tropylium and COT ligands, which is dominant in crystal structures, surpasses an energy of −3.0 kcal mol−1.

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