Modeling of iron activated persulfate oxidation treating reactive azo dye in water matrix

2011 ◽  
Vol 172 (1) ◽  
pp. 109-121 ◽  
Author(s):  
Hrvoje Kusic ◽  
Igor Peternel ◽  
Sime Ukic ◽  
Natalija Koprivanac ◽  
Tomislav Bolanca ◽  
...  
2015 ◽  
Vol 14 (3) ◽  
pp. 528-535 ◽  
Author(s):  
Zacharias Frontistis ◽  
Evroula Hapeshi ◽  
Despo Fatta-Kassinos ◽  
Dionissios Mantzavinos

In this work, the degradation of the azo dye methyl orange in model aqueous solutions by UVC light-induced persulfate oxidation was studied.


Chemosphere ◽  
2021 ◽  
pp. 131787
Author(s):  
Dan Wu ◽  
Hongshuai Kan ◽  
Ying Zhang ◽  
Tiecheng Wang ◽  
Guangzhou Qu ◽  
...  

2021 ◽  
Vol 228 ◽  
pp. 362-375
Author(s):  
Gamze Varank ◽  
Bihter Uykan ◽  
Emine Can-Güven ◽  
Senem Yazici Guvenc

2021 ◽  
Author(s):  
Junyan Wei ◽  
Linning Yin ◽  
Ruijuan Qu ◽  
Gadah Al-Basher ◽  
Xiaoxue Pan ◽  
...  

Abstract An in-depth study on the degradation of bisphenol S (BPS) by both single-walled carbon nanotubes and heat activated persulfate (PS) was investigated in detail. The factors like materials dosage, initial substrate concentration, initial pH and water matrix on removal of BPS were evaluated and 10 µM BPS could be completely removed in 90 min under the optimal conditions of [BPS]0: [PS]0 = 1: 100, T = 25 ℃, pH0 = 7.0, [N-SWCNTs] = 20 mg·L− 1. Fast removal of BPS was also obtained when reaction temperature reached 65 ℃ without catalyst. There were 15 intermediates identified in total; and hydroxylation, sulfate addition, carboxylation, the cleavage of S − C bond and polymerization were considered as the main transformation pathways of BPS in both two systems based on LC-MS analysis. The proportion discrepancy of •OH and SO4•− involved in two systems led to different distribution and abundance of observed products. The results of transition state calculation further confirmed the reaction potential of hydroxylation, hydrogen atom abstraction and sulfate addition, and the minimum reaction barriers were 22.20, 25.06 and 13.85 kJ/mol, respectively. The present work firstly reveals the overall transformation behavior of BPS in radicals-triggered PS system by combining experimental and theoretical study.


2013 ◽  
Vol 263 ◽  
pp. 422-430 ◽  
Author(s):  
Lei Zhou ◽  
Wei Zheng ◽  
Yuefei Ji ◽  
Jinfeng Zhang ◽  
Chao Zeng ◽  
...  

2019 ◽  
Vol 688 ◽  
pp. 1155-1161 ◽  
Author(s):  
Guangyin Zhen ◽  
Yujie Tan ◽  
Taipu Wu ◽  
Jianhui Wang ◽  
Xueqin Lu ◽  
...  

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