Pretreatment of dry-spun acrylic fiber manufacturing wastewater by Fenton process: Optimization, kinetics and mechanisms

2013 ◽  
Vol 218 ◽  
pp. 319-326 ◽  
Author(s):  
Jian Wei ◽  
Yonghui Song ◽  
Xiang Tu ◽  
Le Zhao ◽  
Erquan Zhi
2011 ◽  
Vol 332-334 ◽  
pp. 1582-1585
Author(s):  
Bin Cai ◽  
Xin Wang ◽  
Xiao Li Dai ◽  
Guang Xu Yan ◽  
Shao Hui Guo

A combined process of flocculation and Fenton oxidation was studied for the treatment of polymerization effluents (PME) from the manufacture of dry-spun acrylic fibers. 5 inorganic and 3 organic flocculants were investigated and the optimal regents and conditons were PAC (at 25°C, pH=8 and a dosage of 150 mg/L), and Z7650 (at 25°C, pH=6 and a dosage of 10 mg/L). Under this condition, the COD was removed by 23.1% of the initial 1824 mg/L. The optimum efficiency of Fenton process was determined at 25°C and pH=4 with a reaction time of 90 min. The dosage of H2O2 and the rate of c(H2O2)/c(FeSO4) were respectively 0.53 mol/L and 20:1. Finally, the removal of COD, total nitrogen, ammonia, SO32- and turbidity by the combined process were 64.0%, 99.3%, 99.6%, 99.7% and 89.4% respectively. BOD/COD was also improved from 0.09 to 0.25.


Desalination ◽  
2012 ◽  
Vol 284 ◽  
pp. 62-65 ◽  
Author(s):  
Jin Li ◽  
Zhaokun Luan ◽  
Lian Yu ◽  
Zhongguang Ji

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