The leading aftertreatment technologies for NOx removal from the exhaust gas of lean burn engines, Diesels in particular, are urea based Selective Catalytic Reduction (SCR), Lean NOx Traps (LNT) and Active Lean NOx Catalysts (ALNC). It is generally believed that the SCR technique has the potential of providing the best NOx conversion efficiency relative to the other techniques. Nonetheless, it is crucial that the high conversion efficiencies be achieved with a minimum slippage of unreacted ammonia as tail pipe emissions. This necessitates a precise control over the urea injection process. The complex behavior of the catalyst substrate with respect to adsorption and desorption of ammonia in conjunction with a lack of “stored ammonia” sensing capabilities makes the control problem challenging. In this paper we present a model-based control design approach using a lumped parameter model of an SCR system that includes the essential dynamics of the plant. The model includes the adsorption, desorption and surface coverage dynamics, along with the NOx reduction and ammonia oxidation dynamics based on the relevant chemical reaction rates.
Lean NOx reduction with dodecane over cerium and palladium loaded mordenite
