Selective Uptake of Gaseous Sulfur Trioxide and Mercury in ZnO-CuS Composite at Elevated Temperatures from SO2-rich Flue Gas

2021 ◽  
pp. 132035
Author(s):  
Xingyu Pang ◽  
Wei Liu ◽  
Haomiao Xu ◽  
Qinyuan Hong ◽  
Peng Cui ◽  
...  
RSC Advances ◽  
2020 ◽  
Vol 10 (63) ◽  
pp. 38515-38523
Author(s):  
Rui Zhang ◽  
Xiaodong Si ◽  
Lingling Zhao ◽  
Linjun Yang ◽  
Hao Wu

In this paper, control over the emission of sulfur trioxide aerosols was investigated based on heterogeneous condensation in the wet flue gas desulfurization process.


1983 ◽  
Vol 87 (19) ◽  
pp. 3713-3717 ◽  
Author(s):  
R. D. Brittain ◽  
D. L. Hildenbrand

2017 ◽  
Vol 907 ◽  
pp. 157-163 ◽  
Author(s):  
Maria Cristiana Enescu ◽  
C. Marius Vlădulescu ◽  
Aurel Gaba ◽  
Vasile Bratu ◽  
Elena Valentina Stoian ◽  
...  

This paper analyzes the possibility of reducing the cold end corrosion in boilers and furnaces by using a new type of air combustion pre-heater. Cold end corrosion appears due to catalytic oxidation of the sulfur dioxide to sulfur trioxide and then due to the sulfuric acid condensation at dew point. Calculating dew points of various acid gases and options for reducing cold end corrosion of heat recovery exchangers are presented. For avoiding the cold end corrosion we design a new type of air combustion pre-heater for boilers and furnaces. Also, the tube skin temperature of the first row of pipes of the actual air pre-heater was simulated with this computer program, in order to determine whether this temperature is lower than acid dew point of flue gas. With the simulation for this configuration of the actual combustion air pre-heater, the skin temperature for the first row (for the combustion air flow) of tubes from the upper bundle was TS = 134 °C. A way to reduce the cold end corrosion in the combustion air pre-heaters is raising the temperature of the combustion air at the air pre-heater entrance. This solution involves taking a quantity of preheated air, recirculation and then reintroducing it in the air pre-heater. In the same time, this solution avoiding to use the steam radiator, mounted after the fan, for pre-heating the combustion air from 1°C to 45°C. Thus, the furnaces equipped with the new combustion air pre-heater and modern low NOx burners made a fuel economy about 3%.


Metallurgist ◽  
1971 ◽  
Vol 15 (8) ◽  
pp. 518-520
Author(s):  
A. N. Yasinskii ◽  
R. S. Suprunenko ◽  
L. A. Volkova ◽  
I. D. Shablienko

2009 ◽  
Vol 49 (9) ◽  
pp. 1839-1845 ◽  
Author(s):  
F. Kucera ◽  
J. Jancar

2019 ◽  
Author(s):  
Alex James ◽  
Jake Reynolds ◽  
Dan Reed ◽  
Peter Styring ◽  
Robert Dawson

<div> <p>Functionalised hypercrosslinked polymers (HCPs) with surface areas between 213 – 1124 m<sup>2</sup>/g based on a range of monomers containing different chemical moieties are evaluated for CO<sub>2</sub> capture using a pressure swing adsorption (PSA) methodology under humid conditions and elevated temperatures. The networks demonstrated rapid CO<sub>2</sub> uptake reaching maximum uptakes in under 60 seconds. The most promising networks demonstrating the best selectivity and highest uptakes were applied to a pressure swing setup using simulated flue gas streams. The carbazole, triphenylmethanol and triphenylamine networks were found to be capable of converting a dilute CO<sub>2</sub> stream (> 20 %) into a concentrated stream (> 85 %) after only two pressure swing cycles from 20 bar (adsorption) to 1 bar (desorption). This work demonstrates the ease by which readily synthesised functional porous materials can be successfully applied to a pressure swing methodology and used to separate CO<sub>2</sub> from N<sub>2</sub> from industrially applicable simulated gas streams under more realistic conditions.</p> </div> <br>


Author(s):  
Alex James ◽  
Jake Reynolds ◽  
Dan Reed ◽  
Peter Styring ◽  
Robert Dawson

<div> <p>Functionalised hypercrosslinked polymers (HCPs) with surface areas between 213 – 1124 m<sup>2</sup>/g based on a range of monomers containing different chemical moieties are evaluated for CO<sub>2</sub> capture using a pressure swing adsorption (PSA) methodology under humid conditions and elevated temperatures. The networks demonstrated rapid CO<sub>2</sub> uptake reaching maximum uptakes in under 60 seconds. The most promising networks demonstrating the best selectivity and highest uptakes were applied to a pressure swing setup using simulated flue gas streams. The carbazole, triphenylmethanol and triphenylamine networks were found to be capable of converting a dilute CO<sub>2</sub> stream (> 20 %) into a concentrated stream (> 85 %) after only two pressure swing cycles from 20 bar (adsorption) to 1 bar (desorption). This work demonstrates the ease by which readily synthesised functional porous materials can be successfully applied to a pressure swing methodology and used to separate CO<sub>2</sub> from N<sub>2</sub> from industrially applicable simulated gas streams under more realistic conditions.</p> </div> <br>


1962 ◽  
Vol 36 (3) ◽  
pp. 612-617 ◽  
Author(s):  
R. W. Lovejoy ◽  
J. H. Colwell ◽  
D. F. Eggers ◽  
G. D. Halsey

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