Effect of MgO addition on the crystallization and in vitro bioactivity of glass ceramics in the CaO–MgO–SiO2–P2O5 system

2012 ◽  
Vol 38 (8) ◽  
pp. 6677-6684 ◽  
Author(s):  
J. Ma ◽  
C.Z. Chen ◽  
D.G. Wang ◽  
X. Shao ◽  
C.Z. Wang ◽  
...  
Author(s):  
Gultekin Göller ◽  
Ipek Akin ◽  
A. Kahraman ◽  
Erdem Demirkesen ◽  
M. Urgen

2010 ◽  
Vol 36 (6) ◽  
pp. 1757-1766 ◽  
Author(s):  
C.P. Yoganand ◽  
V. Selvarajan ◽  
Valeria Cannillo ◽  
Antonella Sola ◽  
E. Roumeli ◽  
...  

2006 ◽  
Vol 309-311 ◽  
pp. 325-328 ◽  
Author(s):  
Gültekin Göller ◽  
Ipek Akin ◽  
A. Kahraman ◽  
Erdem Demirkesen ◽  
M. Urgen

In this study; in-vitro bioactivity characterization of machinable glass-ceramics having 85 wt% sodium mica (NaMg3AlSi3O10F2) and 15 wt% fluoroapatite has been carried out. Two different heat treatment procedures are applied to the machinable glass-ceramics. The first one is nucleation at 610°C for 2 hours and crystallization at 1000°C for 3 hours and the second is nucleation at 610°C for 2 hours and crystallization at 1000°C for 4 hours. It is observed that increasing the crystallization time to 4 hours resulted in the increasing the formation of hydroxyapatite layer on surface. According to the microstructural investigations, the morphology of the precipitated crystals are different. In addition, the speed of the precipitation of hydroxyapatite is higher in glass-ceramic B than A. Thin film XRD analysis supports these results.


Materials ◽  
2017 ◽  
Vol 10 (4) ◽  
pp. 425 ◽  
Author(s):  
Amanda De Castro Juraski ◽  
Andrea Cecilia Dorion Rodas ◽  
Hamada Elsayed ◽  
Enrico Bernardo ◽  
Viviane Oliveira Soares ◽  
...  

2012 ◽  
Vol 10 (6) ◽  
pp. 1890-1898 ◽  
Author(s):  
Gabriela Lutišanová ◽  
Martin Palou ◽  
Milan Mikula ◽  
Jana Kozánková

AbstractThe present paper reports the results of the relationship between the surface topography, microstructure and the in vitro bioactivity of samples with and without fluorapatite content in simulated body fluid. Glasses and glass ceramics belonging to the Li2O-SiO2-CaO-P2O5-CaF2 system were prepared by using conventional melting technique following by heat treatment to obtain glass ceramics. This current study demonstrates the benefits of combining two microscopic methods for better investigation of the surface structure. The formation of apatite layer on the surface and the increase in surface roughness proved that the glasses and glass ceramics with bioactive fluorapatite content could satisfy to the requirements for biomaterial applications. The results also showed that the roughness of apatite layer formed after immersion in body fluid on the surface of glasses with fluorapatite was more pronounced than that of equivalent glass ceramic samples cured under the same conditions.


2006 ◽  
Vol 309-311 ◽  
pp. 321-324 ◽  
Author(s):  
Gültekin Göller ◽  
Ipek Akin ◽  
Niyazi Eruslu ◽  
E.S. Kayali

The purpose of this study is to investigate the crystallization behavior and in-vitro bioactivity character of glass ceramics having 3:7 weight ratio of flourapatite (Ca5(PO4)3F) to potassium mica (K2Mg3AlSi3O10F2) as a function of titania addition, and compare the morphology of hydroxycarbonateapatite (HCA) layer formation depending on titania addition on ceramic composition. It is observed from microstructural investigations that there is no morphology change occurred on precipitated HCA layer depending on nucleating agent in glass-ceramics. TF-XRD analysis indicates that after precipitation of initial particulates, crystallization proceeds and crystallization of precipitated HCA phase increases by increasing the time. It is observed that Ca, P ion variation in solution has two stage in terms of precipitation’ first stage represents formation of amorphous HCA and the second stage is related with crystallization. FTIR analysis strongly supports TF-XRD analysis as well.


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