Control of clay mineral properties on hydrocarbon generation of organo-clay complexes: Evidence from high-temperature pyrolysis experiments

2022 ◽  
Vol 216 ◽  
pp. 106368
Author(s):  
Jingong Cai ◽  
Jiazong Du ◽  
Mingshui Song ◽  
Tianzhu Lei ◽  
Xuejun Wang ◽  
...  
Author(s):  
A., C. Prasetyo

Overpressure existence represents a geological hazard; therefore, an accurate pore pressure prediction is critical for well planning and drilling procedures, etc. Overpressure is a geological phenomenon usually generated by two mechanisms, loading (disequilibrium compaction) and unloading mechanisms (diagenesis and hydrocarbon generation) and they are all geological processes. This research was conducted based on analytical and descriptive methods integrated with well data including wireline log, laboratory test and well test data. This research was conducted based on quantitative estimate of pore pressures using the Eaton Method. The stages are determining shale intervals with GR logs, calculating vertical stress/overburden stress values, determining normal compaction trends, making cross plots of sonic logs against density logs, calculating geothermal gradients, analyzing hydrocarbon maturity, and calculating sedimentation rates with burial history. The research conducted an analysis method on the distribution of clay mineral composition to determine depositional environment and its relationship to overpressure. The wells include GAP-01, GAP-02, GAP-03, and GAP-04 which has an overpressure zone range at depth 8501-10988 ft. The pressure value within the 4 wells has a range between 4358-7451 Psi. Overpressure mechanism in the GAP field is caused by non-loading mechanism (clay mineral diagenesis and hydrocarbon maturation). Overpressure distribution is controlled by its stratigraphy. Therefore, it is possible overpressure is spread quite broadly, especially in the low morphology of the “GAP” Field. This relates to the delta depositional environment with thick shale. Based on clay minerals distribution, the northern part (GAP 02 & 03) has more clay mineral content compared to the south and this can be interpreted increasingly towards sea (low energy regime) and facies turned into pro-delta. Overpressure might be found shallower in the north than the south due to higher clay mineral content present to the north.


2022 ◽  
pp. 1-42
Author(s):  
Xiaojun Zhu ◽  
Jingong Cai ◽  
Feng Liu ◽  
Qisheng Zhou ◽  
Yue Zhao ◽  
...  

In natural environments, organic-clay interactions are strong and cause organo-clay composites (a combination between organic matter [OM] and clay minerals) to be one of the predominant forms for OM occurrence, and their interactions greatly influence the hydrocarbon (HC) generation of OM within source rocks. However, despite occurring in nature, dominating the OM occurrence, and having unique HC generation ways, organo-clay composites have rarely been investigated as stand-alone petroleum precursors. To improve this understanding, we have compared the Rock-Eval pyrolysis parameters derived from more than 100 source rocks and their corresponding <2 μm clay-sized fractions (representing organo-clay composites). The results show that all of the Rock-Eval pyrolysis parameters in bulk rocks are closely positively correlated with those in their clay-sized fractions, but in clay-sized fractions the quality of OM for HC generation is poorer, in that the pyrolysable organic carbon levels and hydrogen index values are lower, whereas the residual organic carbon levels are higher than those in bulk rocks. Being integrated with the effects of organic-clay interactions on OM occurrence and HC generation, our results suggest that organo-clay composites are stand-alone petroleum precursors for HC generation occurring in source rocks, even if the source rocks exist in great varieties in their attributes. Our source material for HC generation comprehensively integrates the original OM occurrence and HC generation behavior in natural environments, which differs from kerogen and is much closer to the actual source material of HC generation in source rocks, and it calls for further focus on organic-mineral interactions in studies of petroleum systems.


2020 ◽  
Author(s):  
JIngong Cai ◽  
Jiazong Du ◽  
Tianzhu Lei ◽  
Yingli Li

2018 ◽  
Vol 192 ◽  
pp. 83-90 ◽  
Author(s):  
Xiaojun Zhu ◽  
Jingong Cai ◽  
Guoli Wang ◽  
Mingshui Song

2013 ◽  
Vol 75-76 ◽  
pp. 82-91 ◽  
Author(s):  
Peng Yuan ◽  
Hongmei Liu ◽  
Dong Liu ◽  
Daoyong Tan ◽  
Wenchang Yan ◽  
...  

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