Synthesis of highly surface functionalized monodispersed poly(St/DVB/GMA) nanospheres with soap-free emulsion polymerization followed by facile “click chemistry” with functionalized alkylthiols

2011 ◽  
Vol 380 (1-3) ◽  
pp. 250-256 ◽  
Author(s):  
Xiao-Jie Song ◽  
Jun Hu ◽  
Chang-Chun Wang
Keyword(s):  
Click Chemistry ◽  
Emulsion Polymerization ◽  
Soap Free Emulsion Polymerization

Preparation of Raspberry-Like Polymer/Silica Composite Particles through Cationic Soap-Free Emulsion Polymerization

2012 ◽  
Vol 476-478 ◽  
pp. 1408-1411
Author(s):  
Xin Fan ◽  
Qiu Ju Qin ◽  
Xiu Fang Wen ◽  
Jiang Cheng ◽  
Zhuo Ru Yang
Keyword(s):  
Emulsion Polymerization ◽  
Silica Content ◽  
Silica Particles ◽  
Vital Role ◽  
Silica Sol ◽  
Electrostatic Attraction ◽  
Composite Particles ◽  
Silica Composite ◽  
Soap Free Emulsion Polymerization

In this paper raspberry-like composite particles were prepared via cationic soap-free emulsion polymerization with silica sol as stabilizer and 2-(methacryloyl) ethyltrimethylammonium chloride (MTC) as cationic auxiliary monomer. According to the TGA and TEM results we could find that the electrostatic attraction supplied by MTC played a vital role in the adsorption of silica particles as well as the generation of raspberry-like morphology. The silica content and appearance of composite particles were found to be improved with the increasing amount of silica sol and MTC while varied little with changes of AIBA amount.

Hairy fluorescent nanoparticles from one-pot click chemistry and atom transfer radical emulsion polymerization

2013 ◽  
Vol 63 (2) ◽  
pp. 237-243 ◽  
Author(s):  
Fang Yao ◽  
Guan-Cang Yan ◽  
Li-Qun Xu ◽  
Guo-Dong Fu ◽  
Li-Hong Yin ◽  
...  
Keyword(s):  
Click Chemistry ◽  
Emulsion Polymerization ◽  
Fluorescent Nanoparticles ◽  
Atom Transfer ◽  
One Pot
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