scholarly journals Inkjet printing of surfactant solutions onto thin moving porous media

Author(s):  
Gianmarco Venditti ◽  
Vignesh Murali ◽  
Anton A. Darhuber
1980 ◽  
Vol 20 (03) ◽  
pp. 129-138 ◽  
Author(s):  
A. Satter ◽  
Y.M. Shum ◽  
W.T. Adams ◽  
L.A. Davis

Abstract Because of the importance of chemical flooding operations, the mechanisms of chemical dispersion and adsorption in porous media are of increasing interest to the petroleum industry. This paper presents a mathematical model for simulating presents a mathematical model for simulating chemical transport phenomena in porous rocks; these phenomena include dispersion and either Langmuir phenomena include dispersion and either Langmuir equilibrium or rate-controlled adsorption. The accuracy of this numerical model was verified by comparing the calculated results with those obtained by analytical solutions for a number of limiting cases. The effects of dimensionless dispersion, adsorptive capacity, flow rate, and kinetic rate groups controlling dispersion/adsorption mechanisms were investigated. The utility of the model was demonstrated further by matching experimental results. When adsorption of a chemical is rate-controlled or time-dependent, core flood data obtained at times much shorter than reservoir residence times can lead to a serious underestimation of chemical requirements for the field projects. Introduction Chemical dispersion and adsorption in porous media are of increasing interest to the petroleum industry because of the increasing importance of chemical flooding operations. While dispersion causes mixing and dissipation of a chemical slug, adsorption can result in a real chemical loss to the reservoir; the ultimate success of a chemical recovery process is controlled by the nature and magnitude of the loss. Although diffusion and dispersion have been studied extensively during the past two decades, publications on the adsorption of chemical recovery publications on the adsorption of chemical recovery agents have been limited. The relatively simple case of adsorption of a gas on a clean, homogeneous, solid surface illustrates the complexity of the adsorption phenomenon. The adsorption can be purely physical, purely chemisorption, a combination of physical, purely chemisorption, a combination of both, or an intermediate type. The adsorption of polymer and surfactant solutions on porous rocks is polymer and surfactant solutions on porous rocks is complicated by the physiochemical properties of the solutions and rocks and by the nature of the pore structure of the rock matrix. Nevertheless, adsorption from dilute aqueous-phase solutions can be described by the Langmuir equilibrium isotherm for a variety of chemicals, including many surfactants and polymers. These chemicals can sometimes exhibit adsorptions that are significantly rate-controlled or time-dependent rather than instantaneous. The classical model for rate-controlled adsorption was proposed by Langmuir. This paper presents numerical solutions to the transport equations for dispersion and adsorption in porous media, considering Langmuir equilibrium porous media, considering Langmuir equilibrium adsorption as well as Langmuir rate-controlled adsorption. The effects of various process parameters on adsorption also were investigated. parameters on adsorption also were investigated. Model Development Transport Equations A chemical transport equation chacterizing dispersion and adsorption of a chemical solution flowing through a porous medium can be derived by a mass balance as follows. 2C q C C 1- CrD ----- - ---- --- = ----- + ---- pr -----.x2 A x t t...................................(1) The dispersion coefficient, D, can be expressed as qD= (---)= u.................................(2)A SPEJ P. 129


1978 ◽  
Author(s):  
M. Fernandez ◽  
M. El Emary ◽  
W.H. Wade ◽  
F.J. Trogus ◽  
R.S. Schechter

1968 ◽  
Vol 8 (04) ◽  
pp. 359-369 ◽  
Author(s):  
L.W. Holm

Abstract This study shows that in the presence of foam, gas and liquid flow separately through porous media representative of reservoir rock. These results were obtained by using tracer techniques to measure the flow of the gas and liquid comprising the foam. Foam does not flow through the porous medium as a body even when the liquid and gas are combined outside the system and injected as foam Instead the liquid and gas forming the foam separate as the foam films break and then re-form in the porous system. Liquid moves through the porous medium via the film network of the bubbles and gas moves progressively through the system by breaking and re-forming bubbles throughout the length of the flow path. The flow rates of the gas and liquid are a function of the number and strength of the films in the porous medium. There is no free flow of gas; i.e., no continuous gas phase. On the basis of these results, foam can be expected to improve a waterflood or gas drive by decreasing the permeability of the reservoir rock to a displacing liquid or gas. This improves the mobility ratio and thus the conformance of the flood. Introduction Foam is formed when gas and a solution of a surface active agent are injected into a porous medium either simultaneously or intermittently. During the past few years, several papers have been published on the subject of foam flow in porous media. Foam has been used successfully in the removal of capillary water blocks from producing formations. The use of foam in gas storage reservoirs to reduce gas leaks and to increase storage capacity has been considered in recent years. Foam has also been investigated as an oil displacing agent, and as an agent to improve the mobility ratio in a waterflood. However, the mechanism by which the gas and liquid phases comprising the foam flow through a porous medium has not been described adequately. Normally, when two immiscible phases (gas and liquid) flow concurrently through a porous medium, each phase follows separate paths or channels. At given saturations of the two phases, a certain number of channels are available to each phase, and as saturations change, the number and configuration of the channels available for each phase also change. The effective permeability of each phase is a function of the saturation of that phase only, and the flow of each phase can be described by Darcy's law. When foam is present, the effective permeability of the porous medium to each phase is greatly reduced compared with permeabilities measured in the absence of foam. Based upon the observed flow of surfactant solutions and gas in capillaries, it has been concluded that the gas and liquid may flow separately or they may flow combined as foam. At least four mechanisms have been postulated to explain how fluids flow with foam present:A large portion of the gas is trapped in the porous medium and a small fraction flows as free gas, following Darcy's law.The foam structure moves as a body; the rate of gas flow is the same as the rate of liquid flow.Gas flows as a discontinuous phase by breaking and re-forming films. Liquid flows as a free phase.A portion of the liquid and gas move as a foam body while excess surfactant solution moves as a free phase. It also has been suggested that different flow mechanisms exist for high quality (dry) foams made from dilute surfactant solutions and for foams made from more concentrated solutions. Studies conducted on the flow of foam through capillaries have shown that a plug-type flow occurs and that foam flows as a body.


2019 ◽  
Vol 3 (1) ◽  
pp. 14 ◽  
Author(s):  
Phillip Johnson ◽  
Toby Routledge ◽  
Anna Trybala ◽  
Mauro Vaccaro ◽  
Victor Starov

The wetting properties of aqueous solutions of a commercially available surfactant at various concentrations on porous media are investigated using the KRUSS DSA100 shape analyzer and the ADVANCED software to process the data. Time evolution of both the contact angle and drop base diameter at each surfactant concentration after deposition were monitored. Three different porous substrates (sponges) were examined. The sponges used were a car sponge, dish sponge and audio sponge. The sponges were investigated both dry and at different degrees of saturation, that is, the amount of water absorbed into the sponge. It was found that pure distilled water droplets deposited on the dry porous media showed non-wetting. However, if droplets of surfactant solutions were deposited, then a change to a complete wetting case was found at all surfactant concentrations used. It has been observed that for all sponges, no matter the degree of saturation, they display a minimum contact angle after which the droplet is rapidly absorbed into the porous media.


1981 ◽  
Vol 21 (06) ◽  
pp. 709-720 ◽  
Author(s):  
B. Kalpakci ◽  
E.E. Klaus ◽  
J.L. Duda ◽  
R. Nagarajan

Kalpakci, B., SPE, Standard Oil Co. (Ohio) Klaus, E.E., Pennsylvania State U. Pennsylvania State U. Duda, J.L., SPE, Pennsylvania State U. Pennsylvania State U. Nagarajan, R., Pennsylvania State U. Pennsylvania State U. DECEMBER 1981 Abstract This paper presents results of a study on flow properties of surfactant solutions in porous media, properties of surfactant solutions in porous media, using the Penn State porous media viscometer. The effects of permeability, shear rate, and surface characteristics of porous media on the flow of oil- and water-external microemulsions, as well as surfactant solutions with lamellar structures, are examined. Untreated Bradford and Berea sand- stones, oil- and water-wet treated sandstones, and filter papers are used as porous media. The study shows that the effective viscosity of the surfactant solution (as measured in porous media), on the basis of initial permeabilities, is greater than the bulk viscosity (as measured by conventional viscometers). This increase is small for Newtonian surfactant solutions but is quite substantial for non- Newtonian surfactant solutions. The difference between bulk and effective viscosities of Newtonian surfactant solutions is eliminated when the effective viscosity is determined on the basis of the final permeability of the porous medium to calibration permeability of the porous medium to calibration solution. This indicates that the permeability of the porous medium during now of these Newtonian porous medium during now of these Newtonian surfactant solutions is equal to that during flow of postcalibration solutions. In contrast, in the case of postcalibration solutions. In contrast, in the case of the non-Newtonian surfactant solution with lamellar structures, the effective viscosity based on the final permeability remains higher than the bulk viscosity permeability remains higher than the bulk viscosity of the solution. Plausible explanations for the lower permeability during surfactant flow compared with permeability during surfactant flow compared with the final permeability, in this case, are discussed. It is found that the flow of surfactant solutions causes a permanent decrease in the permeability of the porous. medium. Initial permeability is not restored even by thorough flushing of the porous medium with surfactant-free brine solution. Residual permeability reductions of 2 to 51% are observed. permeability reductions of 2 to 51% are observed. The residual permeability reduction increases with decreasing initial permeability. The residual permeability reduction is relatively insensitive to the type permeability reduction is relatively insensitive to the type of surfactant solution. However, it depends on surface characteristics of the porous medium and decreases in this order: untreatedfired is greater th an oil-wet treated. Introduction According to Gogarty, about 60% of the potential oil reserves are estimated to be amenable to chemical flooding with surfactant and polymers. In surfactant/polymer flooding, the interaction of various chemicals with each other and with reservoir fluids and rocks, the permeability, the porosity, and the operating conditions are critical factors in determining the effectiveness of the process. Many studies of surfactant systems have been carried out relating to phase behavior, interfacial tension, and retention or adsorption characteristics. But only a few studies have been conducted on flow characteristics in porous media of surfactant fluids prepared with petroleum sulfonates, hydrocarbons, prepared with petroleum sulfonates, hydrocarbons, water, and electrolytes. These latter studies have not examined fully the flow characteristics over a wide range of permeabilities and shear rates, the influence of the permeability of porous media on the residual permeability reduction, and the influence of surface permeability reduction, and the influence of surface characteristics of porous media. Considering that sufficient viscosity level is an essential factor in mobility control during surfactant flooding, the importance of the rheology of surfactant solution in porous media is quite obvious. Information on porous media is quite obvious. Information on injectivity, effective viscosity, and permeability modification during the flow of surfactant solutions is also essential. SPEJ P. 709


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