Effect of impulse high voltage anodic and cathodic electrochemical treatment of a glassy carbon electrode on the oxygen reduction reaction in alkaline media

2018 ◽  
Vol 96 ◽  
pp. 57-60 ◽  
Author(s):  
Alexander G. Krivenko ◽  
Roman A. Manzhos ◽  
Svetlana G. Protasova
Author(s):  
Turgut Sönmez ◽  
Kendra Solveig Belthle ◽  
Andree Iemhoff ◽  
Jan Uecker ◽  
Jens Artz ◽  
...  

A covalent triazine framework coated on glassy carbon electrode performs high catalytic activity towards the ORR.


2020 ◽  
Vol 45 (38) ◽  
pp. 18850-18858
Author(s):  
M.M. Shahid ◽  
Yiqiang Zhan ◽  
Mahdi Alizadeh ◽  
Suresh Sagadevan ◽  
Suriati Paiman ◽  
...  

2020 ◽  
Vol 9 (1) ◽  
pp. 843-852
Author(s):  
Hunan Jiang ◽  
Jinyang Li ◽  
Mengni Liang ◽  
Hanpeng Deng ◽  
Zuowan Zhou

AbstractAlthough Fe–N/C catalysts have received increasing attention in recent years for oxygen reduction reaction (ORR), it is still challenging to precisely control the active sites during the preparation. Herein, we report FexN@RGO catalysts with the size of 2–6 nm derived from the pyrolysis of graphene oxide and 1,1′-diacetylferrocene as C and Fe precursors under the NH3/Ar atmosphere as N source. The 1,1′-diacetylferrocene transforms to Fe3O4 at 600°C and transforms to Fe3N and Fe2N at 700°C and 800°C, respectively. The as-prepared FexN@RGO catalysts exhibited superior electrocatalytic activities in acidic and alkaline media compared with the commercial 10% Pt/C, in terms of electrochemical surface area, onset potential, half-wave potential, number of electrons transferred, kinetic current density, and exchange current density. In addition, the stability of FGN-8 also outperformed commercial 10% Pt/C after 10000 cycles, which demonstrates the as-prepared FexN@RGO as durable and active ORR catalysts in acidic media.


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