The effect of additive of Lewis acid type on lithium–gel electrolyte characteristics

Molybdenum(VI) dichloride dioxide (MoO2Cl2), and its addition complexes [MoO2Cl2(L)n; L = neutral ligand], are commercially or easily available and inexpensive transition-metal complexes based on a non-noble metal that can be applied as catalysts for various organic transformations. This short review aims to present the most significant breakthroughs in this field.1 Introduction2 Preparation and Reactivity of MoO2Cl2(L)n Complexes2.1 Synthesis and Structure2.2 Reactivity of Dichlorodioxomolybdenum(VI) Complexes3 Redox Processes Catalyzed by MoO2Cl2(L)n Complexes3.1 Deoxygenation Reactions Using Phosphorus Compounds3.2 Deoxygenation and Hydrosilylation Reactions Using Silanes3.3 Reduction Reactions Using Hydrogen3.4 Deoxygenation Reactions with Boranes and Thiols3.5 Reduction Reactions with Glycols3.6 Oxidation Reactions4 Ambiphilic Reactivity of MoO2Cl2 4.1 Amphoteric Lewis Acid–Lewis Base Catalyzed Reactions4.2 Lewis Acid Type Catalyzed Reactions5 Conclusion and Perspective

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Comparison study of lewis acid type catalysts on the esterification of octanoic acid and n-octyl alcohol

Chemical Engineering & Technology ◽

10.1002/ceat.270190611 ◽

1996 ◽

Vol 19 (6) ◽

pp. 538-542 ◽

Cited By ~ 7

Author(s):

Ana María Bahamonde Santos ◽

Mercedes Martínez ◽

José Aracil Mira

Keyword(s):

Lewis Acid ◽

Octanoic Acid ◽

Comparison Study ◽

Acid Type

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Effects of Lewis-acid polymer on the electrochemical properties of alkylphosphate-based non-flammable gel electrolyte

Journal of Power Sources ◽

10.1016/j.jpowsour.2009.05.011 ◽

2009 ◽

Vol 194 (1) ◽

pp. 531-535 ◽

Cited By ~ 11

Author(s):

Boor Singh Lalia ◽

Nobuko Yoshimoto ◽

Minato Egashira ◽

Masayuki Morita

Keyword(s):

Electrochemical Properties ◽

Lewis Acid ◽

Gel Electrolyte

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Short-Wave Infrared-Sensing Organic Phototransistors with a Triarylamine-Based Polymer Doped with a Lewis Acid-Type Small Molecule

ACS Applied Materials & Interfaces ◽

10.1021/acsami.1c00472 ◽

2021 ◽

Vol 13 (16) ◽

pp. 19064-19071

Author(s):

Chulyeon Lee ◽

Hwajeong Kim ◽

Youngkyoo Kim

Keyword(s):

Small Molecule ◽

Lewis Acid ◽

Short Wave ◽

Infrared Sensing ◽

Acid Type ◽

Short Wave Infrared

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Influence of Preparation Conditions on the Acidity of WO3/ZrO2 Solid Superacid

Advanced Materials Research ◽

10.4028/www.scientific.net/amr.233-235.1502 ◽

2011 ◽

Vol 233-235 ◽

pp. 1502-1506 ◽

Cited By ~ 1

Author(s):

Ping Xu ◽

Min Wei Wang ◽

Jia Wei Qu ◽

Ren Lang Wang ◽

Jian Wang

Keyword(s):

Lewis Acid ◽

Acid Sites ◽

Acid Strength ◽

Lewis Acid Sites ◽

Solid Superacid ◽

Preparation Conditions ◽

Acid Type ◽

Loading Amount ◽

Superacid Catalysts ◽

Adsorption Desorption

WO3/ZrO2 solid superacid catalysts were prepared by coprecipitation and impregnation, then were characterized by XRD, N2 adsorption-desorption, Hammett indicator and pyridine chemisorption IR. The acid strength, acid type, acid volume, etc were compared under the different preparation conditions. The results indicated that the catalyst prepared by coprecipitation had stronger acid strength than the catalyst prepared by impregnation. The samples prepared by impregnation had more Lewis acid sites. With the increasing of the W/Zr ratio, the acid strength tended to increase at first and then decrease, and the catalyst with 10% WO3 loading amount had the strongest acidity. The higher the calcination temperature, the less the Lewis acid sites.

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