Service life test of non-noble metal composite cathodes for hydrogen evolution in sodium hydroxide solution

2012 ◽  
Vol 63 ◽  
pp. 124-130 ◽  
Author(s):  
V.D. Jović ◽  
U. Lačnjevac ◽  
B.M. Jović ◽  
N.V. Krstajić
2013 ◽  
Vol 78 (5) ◽  
pp. 689-700 ◽  
Author(s):  
Vladimir Jovic ◽  
Uros Lacnjevac ◽  
Borka Jovic ◽  
Ljiljana Gajic-Krstajic ◽  
Nedeljko Krstajic

In this work the effect of aging of the electrolyte for electrodeposition of Ni-MoO2 composite coatings on their morphology (scanning electron microscopy), chemical composition (energy-dispersive X-ray spectroscopy), polarization characteristics and the ?service life? test performance for the hydrogen evolution reaction (HER) in 32 mass % NaOH at 90?C was investigated. Polarization characteristics and results of the ?service life? test of Ni-MoO2 composite coatings obtained after different aging periods of the electrolyte for deposition (suspension of MoO2 powder particles in the solution containing 2 M NH4Cl + 0.2 M NiCl2) were compared with that recorded for De Nora?s commercial Ni+RuO2 cathode coating (DN). It was shown that aging of the electrolyte did not influence the morphology and chemical composition of Ni-MoO2 composite coatings electrodeposited under simulated conditions for their industrial production, while polarization characteristics for the HER were influenced. The best coating, obtained after 180 days of the electrolyte aging, showed completely different (layered) structure of the deposit and significantly better performance than the commercial DN electrode during the ?service life? test.


1982 ◽  
Vol 35 (8) ◽  
pp. 1727 ◽  
Author(s):  
J Rosevear ◽  
JFK Wilshire

The sodium salt of 4-amino-3-nitrobenzenesulfonic acid (O-nitroaniline-p-sulfonic acid) has been prepared by the action of dilute sodium hydroxide solution on ethyl [(4-chlorosulfonyl-2-nitro)- phenyllcarbamate. Central to this synthesis is the finding that the N-ethoxycarbonyl group, when located ortho to a nitro group (but not to a bromo group), is readily removed by dilute sodium hydroxide solution.


2015 ◽  
Vol 22 (12) ◽  
pp. 4545-4550 ◽  
Author(s):  
Chong-qing Wang ◽  
Hui Wang ◽  
Guo-hua Gu ◽  
Jian-gang Fu ◽  
You-nian Liu

1997 ◽  
Vol 1997 (Supplement94) ◽  
pp. 217-225
Author(s):  
Tatsuya Fujiyoshi ◽  
Hiroyuki Masuda ◽  
Tokuji Nishinaka ◽  
Tetsuo Futami ◽  
Hiromi Shibuya

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