Thermodynamic evaluation and multi-objective optimization of molten carbonate fuel cell-supercritical CO 2 Brayton cycle hybrid system

Abstract The production of liquefied natural gas (LNG) is a high energy-consuming process. The study of ways to reduce energy consumption and consequently to reduce operational costs is imperative. Toward this purpose, this study proposes a hybrid system adopting a mixed refrigerant for the liquefaction of natural gas that is precooled with an ammonia/water absorption refrigeration (AR) cycle utilizing the exhaust heat of a molten carbonate fuel cell, 700°C and 2.74 bar, coupled with a gas turbine and a bottoming Brayton super-critical carbon dioxide cycle. The inauguration of the ammonia/water AR cycle to the LNG process increases the cooling load of the cycle by 10%, providing a 28.3-MW cooling load duty while having a 0.45 coefficient of performance. Employing the hybrid system reduces energy consumption, attaining 85% overall thermal efficiency, 53% electrical efficiency and 35% fuel cell efficiency. The hybrid system produces 6300 kg.mol.h−1 of LNG and 146.55 MW of electrical power. Thereafter, exergy and sensitivity analyses are implemented and, accordingly, the fuel cell had an 83% share of the exergy destruction and the whole system obtained a 95% exergy efficiency.

Download Full-text

Performance Evaluation of a Molten Carbonate Fuel Cell/Micro Gas Turbine Hybrid System With Oxy-Combustion Carbon Capture

Volume 3: Coal, Biomass and Alternative Fuels; Cycle Innovations; Electric Power; Industrial and Cogeneration Applications; Organic Rankine Cycle Power Systems ◽

10.1115/gt2017-63859 ◽

2017 ◽

Author(s):

Ji Ho Ahn ◽

Tong Seop Kim

Keyword(s):

Carbon Dioxide ◽

Fuel Cell ◽

Gas Turbine ◽

Hybrid System ◽

Carbon Capture ◽

Molten Carbonate Fuel Cell ◽

Design Parameters ◽

Molten Carbonate ◽

Micro Gas Turbine ◽

Carbonate Fuel Cell

Owing to the increasing consumption of fossil fuels and emission of greenhouse gases, interests in highly efficient and low carbon emitting power systems are growing fast. Several research groups have been suggesting advanced systems based on fuel cells and have also been applying carbon capture and storage technology to satisfy the demand for clean energy. In this study, the performance of a hybrid system, which is a combination of a molten carbonate fuel cell (MCFC) with oxy-combustion carbon capture and an indirectly fired micro gas turbine (MGT) was predicted. A 2.5MW MCFC system that is used in commercial applications was used as the reference system so that the results of the study could be applicable to practical situations. The ambient pressure type hybrid system was modeled by referring to the design parameters of an MGT that is currently being developed. A semi-closed type design characterized by flow recirculation was adopted for this hybrid system. A part of the recirculating gas is converted into liquefied carbon dioxide and captured for storage at the carbon separation unit. Almost 100% carbon dioxide capture is possible with this system. In these systems, the output power of the fuel cell is larger than in the normal hybrid system without carbon capture because the partial pressure of carbon dioxide increases. The increased cell power partially compensates for the power loss due to the carbon capture and MGT power reduction. The dependence of net system efficiency of the oxy-hybrid on compressor pressure ratio is marginal, especially beyond an optimal value.

Download Full-text

Performance Evaluation of a Molten Carbonate Fuel Cell/Micro Gas Turbine Hybrid System With Oxy-Combustion Carbon Capture

Journal of Engineering for Gas Turbines and Power ◽

10.1115/1.4038038 ◽

2017 ◽

Vol 140 (4) ◽

Cited By ~ 3

Author(s):

Ji Ho Ahn ◽

Tong Seop Kim

Keyword(s):

Carbon Dioxide ◽

Fuel Cell ◽

Gas Turbine ◽

Hybrid System ◽

Carbon Capture ◽

Molten Carbonate Fuel Cell ◽

Design Parameters ◽

Molten Carbonate ◽

Micro Gas Turbine ◽

Carbonate Fuel Cell

Owing to the increasing consumption of fossil fuels and emission of greenhouse gases, interests in highly efficient and low carbon emitting power systems are growing fast. Several research groups have been suggesting advanced systems based on fuel cells and have also been applying carbon capture and storage technology to satisfy the demand for clean energy. In this study, the performance of a hybrid system, which is a combination of a molten carbonate fuel cell (MCFC) with oxy-combustion carbon capture and an indirectly fired micro gas turbine (MGT), was predicted. A 2.5 MW MCFC system that is used in commercial applications was used as the reference system so that the results of the study could be applied to practical situations. The ambient pressure type hybrid system was modeled by referring to the design parameters of an MGT that is currently being developed. A semi-closed type design characterized by flow recirculation was adopted for this hybrid system. A part of the recirculating gas is converted into liquefied carbon dioxide and captured for storage at the carbon separation unit (CSU). Almost 100% carbon dioxide capture is possible with this system. In these systems, the output power of the fuel cell is larger than in the normal hybrid system without carbon capture because the partial pressure of carbon dioxide increases. The increased cell power partially compensates for the power loss due to the carbon capture and MGT power reduction. The dependence of net system efficiency of the oxy-hybrid on compressor pressure ratio is marginal, especially beyond an optimal value.

Download Full-text