Heterogeneous catalysis for biodiesel production from Jatropha curcas oil (JCO)

Energy ◽  
2011 ◽  
Vol 36 (5) ◽  
pp. 2693-2700 ◽  
Author(s):  
Abebe K. Endalew ◽  
Yohannes Kiros ◽  
Rolando Zanzi
2012 ◽  
Vol 24 (7) ◽  
pp. 158-160 ◽  
Author(s):  
Mohamed M. Soumanou ◽  
Sebastien T. Djenontin ◽  
Fidele P. Tchobo ◽  
Dominique C. K. Sohounhloue ◽  
Uwe T. Bornscheuer

2019 ◽  
Vol 49 (4) ◽  
pp. 275-281
Author(s):  
María Fernanda Laborde ◽  
Laura Ivana Orifici ◽  
José Alberto Bandoni ◽  
Medardo Serna Gonzalez ◽  
José María Ponce Ortega ◽  
...  

In this paper was assessed the potential of biodiesel production from Jatropha curcas oil. The proposed process was simulated in the software Aspen Plus™ involving the stages of trans-esterification reaction, methanol recovering, purification of the obtained methyl esters, catalyst removing, purifying of glycerol and the energy integration through heat exchange networks (HEN). The biodiesel process was carried out through the catalytic reaction of transesterification of Jatropha oil with methanol using a molar ratio of methanol oil of 6:1, and with 1% w/w of NaOH (related to oil mass) as catalyst. Under these conditions, it is technologically feasible to carry out the production of biodiesel. With energy integration through the synthesis of HENs, reductions of 100% and 41.3% of hot and cold utilities were achieved. This way, the utility cost decreases 70.92%. The net present value (NPV) for the integrated process was 70.64% higher than the one corresponding to the non-integrated process under the same production conditions.


2016 ◽  
Vol 9 (1) ◽  
pp. 50-55
Author(s):  
Saibun Sitorus

The research about utilization ash of coconut husk as source of base catalyst in aplication for reaction of transesterification from Jatropha curcas oil has been researched. Content of base compound in coconut husk ash was analyzed by AAS and acidy alkalimetry. The base catalyst was extracted using methanol, for transesterification reaction of Jatropha curcas oil. This method of biodiesel production by transesterification process used coconut husk ash catalyst by weight variation as much as 2%, 4%, 6%, 8% and 10% (w/w). Analysis of the quality of biodiesel is done with quality parameters acid number, iodine number, density, viscosity and water content in accordance with SNI 04-7182-2006 standards. The result of the research showed that potassium concentration as carbonat salt in the ash of coconut husk was 17,4% (w/w) and the conversion of biodiesel obtained from each catalyst in a row is 43,62%; 78,45%; 76,22%; 75,69% and 63,27% (w/w). Biodiesel optimum results obtained with the addition of the catalyst are 4% with density values of 0.86 (g / mL), the viscosity value of 3.23 (cSt), the value of water content 0.0352%, 0.12 acid number (mg KOH / g) and iodine number of 8.23 (g I2 / 100 g).The research about utilization ash of coconut husk as source of base catalyst in aplication for reaction of transesterification from Jatropha curcas oil has been researched. Content of base compound in coconut husk ash was analyzed by AAS and acidy alkalimetry. The base catalyst was extracted using methanol, for transesterification reaction of Jatropha curcas oil. This method of biodiesel production by transesterification process used coconut husk ash catalyst by weight variation as much as 2%, 4%, 6%, 8% and 10% (w/w). Analysis of the quality of biodiesel is done with quality parameters acid number, iodine number, density, viscosity and water content in accordance with SNI 04-7182-2006 standards. The result of the research showed that potassium concentration as carbonat salt in the ash of coconut husk was 17,4% (w/w) and the conversion of biodiesel obtained from each catalyst in a row is 43,62%; 78,45%; 76,22%; 75,69% and 63,27% (w/w). Biodiesel optimum results obtained with the addition of the catalyst are 4% with density values of 0.86 (g / mL), the viscosity value of 3.23 (cSt), the value of water content 0.0352%, 0.12 acid number (mg KOH / g) and iodine number of 8.23 (g I2 / 100 g).ABSTRAKPenelitian tentang pemanfaatan abu sabut kelapa sebagai sumber katalis basa pada aplikasi reaksi transesterifikasi minyak biji jarak pagar (Jatropha curcas. L) telah dilakukan. Karakterisasi kadar basa dalam sabut kelapa dilakukan dengan AAS dan alkalinitas. Katalis basa diperoleh dengan pengadukan abu sabut kelapa dalam metanol dan selanjutnya digunakan untuk reaksi transesterifikasi minyak biji jarak pagar (Jatropha curcas. L). Metode pembuatan biodiesel ini dengan transesterifikasi menggunakan katalis abu sabut kelapa dengan variasi berat sebanyak 2%, 4%, 5%, 6%, 8% dan 10% (b/b). Analisis kualitas dari biodiesel dilakukan dengan parameter mutu bilangan asam, bilangan iod, densitas, viskositas dan kadar air sesuai dengan standar SNI 04-7182-2006. Hasil penelitian menunjukkan bahwa kadar kalium dalam bentuk kalium karbonat dalam abu sabut kelapa sebesar 17,4% (b/b) dan konversi biodiesel yang diperoleh dari masing masing katalis berturut-turut adalah 43,62%; 78,45%; 76,22%; 75,69% dan 63,27% (b/b). Hasil optimum biodiesel diperoleh dengan penambahan katalis 4% dengan nilai densitas 0,86 (g/mL), nilai viskositas 3,23 (cSt), nilai kadar air 0,0352%, bilangan asam 0,12 (mg KOH/g) dan bilangan iod sebesar 8,23 (g I2/100 g). Kata kunci :    Abu sabut kelapa, biodiesel, transesterifikasi, minyak biji jarak pagar(Jatropha curcas. L)


2013 ◽  
Vol 291-294 ◽  
pp. 207-211
Author(s):  
Xue Jun Liu ◽  
Hai Yan Zhang ◽  
Ning Ai ◽  
Mei Zhen Lu ◽  
Yu Min Li ◽  
...  

The acid value of jatropha curcas oil is 9.41mgKOH/g. The most of fatty acids should be removed if base catalysts are adopted to catalyze the transesterification reaction for biodiesel production in case of soap formation. In this study, methanol and ethanol were adopted to extract the fatty acids in jatropha curcas oil. Then, it was catalyzed by calcium methoxide for biodiesel production. The extracted fatty acids can be used to produce biodiesel at supercritical or sulfuric acid conditions. The results indicated that the acid value of jatropha curcas oil decrease to 0.31 mgKOH/g from 9.41 mgKOH/g using ethanol extraction for 3 times at 25°C. The biodiesel yield exceeded 96% using solid base catalyst. The advantages of methanol and ethanol extractions are low oil loss and high biodiesel yield.


2015 ◽  
Vol 6 (2) ◽  
pp. 181
Author(s):  
Ifeanyi Francis Offor ◽  
Richard Chukwuemeka Ehiri ◽  
Chihurumnanya Ola Ude

2021 ◽  
Vol 1833 (1) ◽  
pp. 012041
Author(s):  
Y W Mirzayanti ◽  
N P Asri ◽  
L Marlinda ◽  
M A l Muttaqii

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