Synthesis, performance and mechanism of nanoporous Fe-(1,3,5-tricarboxylic acid) metal-organic framework in the removal of anionic dyes from water

Author(s):  
José Elías Conde-González ◽  
Eladia M. Peña-Méndez ◽  
Alba M. Melián-Fernández ◽  
Josef Havel ◽  
Victoria Salvadó
RSC Advances ◽  
2020 ◽  
Vol 10 (61) ◽  
pp. 37028-37034
Author(s):  
Jianyu Zhang ◽  
Chunli Su ◽  
Xianjun Xie ◽  
Peng Liu ◽  
Md. Enamul Huq

HKUST-1 is a copper-based metal–organic framework (MOF). The HKUST-1/PMS/Vis system can effectively degrade RhB and MB but accomplish poor removal of AO7 and MR, which is attributed to the repulsion between surface charges.


2017 ◽  
Vol 46 (31) ◽  
pp. 10197-10201 ◽  
Author(s):  
Jun-Jiao Li ◽  
Chong-Chen Wang ◽  
Hui-fen Fu ◽  
Jing-Rui Cui ◽  
Peng Xu ◽  
...  

MOF BUC-17 was used to conduct efficiently selective uptake of organic dyes, and achieve rapid separation of CR and MB from their mixture.


2016 ◽  
Vol 5 (6) ◽  
Author(s):  
Nguyen Thu Phuong ◽  
Claudine Buess-Herman ◽  
Nguyen Thi Thom ◽  
Pham Thi Nam ◽  
Tran Dai Lam ◽  
...  

AbstractA metal organic framework (MOF) material based on Cu-BTC, which is formed from Cu and benzene-1,3,5-tricarboxylic acid (H


2021 ◽  
Author(s):  
Huan Doan ◽  
Hoa Thi Nguyen ◽  
Valeska Ting ◽  
Shaoliang Guan ◽  
Jean-Charles Eloi ◽  
...  

<p>Introducing heterostructure to graphitic carbon nitrides (g-C<sub>3</sub>N<sub>4</sub>) can improve the activity of visible-light-driven catalysts for efficient treatment of multiple toxic pollutants in water. Here we report for the first time that a complex material can be constructed from an oxygen-doped g-C<sub>3</sub>N<sub>4</sub> and MIL-53(Fe) metal-organic framework using a facile hydrothermal synthesis and recycled polyethylene terephthalate from plastic waste. The novel multi-walled nanotube structure of the O-g-C<sub>3</sub>N<sub>4</sub>/MIL-53(Fe) composite which enables unique interfacial charge transfer at the heterojunction showed an obvious enhancement in separation efficiency of the photochemical electron-hole pairs. This resulted in narrow bandgap energy (2.30 eV compared to 2.55 eV in O-g-C<sub>3</sub>N<sub>4</sub>), high photocurrent intensity (0.17 mA cm<sup>-2 </sup>compared to 0.12 mA cm<sup>-2</sup> and 0.09 mA cm<sup>-2</sup> in MIL-53(Fe) and O-g-C<sub>3</sub>N<sub>4</sub>, respectively), and excellent catalytic performance in the photodegradation of anionic azo dyes (95% RR 195 and 99% RY 145 degraded after 4 h, and only a minor change in the efficiency observed after four consecutive tests). These results demonstrate the development of new catalysts made from waste feedstocks that show high stability, ease of fabrication and can operate in natural light for environmental remediation.</p>


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