Calcium isotopes in caves as a proxy for aridity: Modern calibration and application to the 8.2 kyr event

2016 ◽  
Vol 443 ◽  
pp. 129-138 ◽  
Author(s):  
R.A. Owen ◽  
C.C. Day ◽  
C.-Y. Hu ◽  
Y.-H. Liu ◽  
M.D. Pointing ◽  
...  
2008 ◽  
Vol 268 (1-2) ◽  
pp. 124-136 ◽  
Author(s):  
Elizabeth M. Griffith ◽  
Adina Paytan ◽  
Reinhard Kozdon ◽  
Anton Eisenhauer ◽  
A. Christina Ravelo

1979 ◽  
Vol 85 (2-3) ◽  
pp. 167-171 ◽  
Author(s):  
B.A. Brown ◽  
S.E. Massen ◽  
P.E. Hodgson

1972 ◽  
Vol 27 (2) ◽  
pp. 126-133 ◽  
Author(s):  
Klaus Gustav Heumann ◽  
Karl Heinrich Lieser

The following heterogeneous exchange equilibria have been examined for isotopic effects: CaCO3/Ca(aq.)2⊕. Ca-GBHA/Ca(aq.)2⊕ and Ca(Dowex 50)2⊕/Ca(aq.)2⊕ (GBHA = glyoxal-bis (2-hydroxyanil)). The isotopic ratios 44Ca/40Ca and 48Ca/40Ca were determined by means of a mass spectrometer with a thermal ion source. In the system CaCO3/Ca(aq.)2⊕, the elementary separation factor was found to be less than 1‰ or 0,5‰ per mass unit, respectively.For the exchange in the system Ca-GBHA/Ca(aq.)2⊕ in the concentration range from 0.011 to 0.84 M an elementary separation factor less than 1‰ per mass unit was found; from a three-stage experiment at a calcium concentration of 1.23 M it was concluded that the elementary isotopic effect is less than 0.4‰ per mass unit. Therefore no isotopic fractionation is to be expected for precipitation of inorganic or organic calcium salts.An enrichment of the heavier calcium isotopes in the solution was found in the case of the exchange in a Dowex 50-X12 loaded column. The isotopic effect depends on the concentration of the hydrochloric acid used as the eluent.


1970 ◽  
Vol 24 (4) ◽  
pp. 145-148 ◽  
Author(s):  
L. R. B. Elton ◽  
S. J. Webb

1983 ◽  
Vol 27 (1) ◽  
pp. 405-407 ◽  
Author(s):  
A. Saha ◽  
Kamal K. Seth ◽  
H. Nann

1976 ◽  
Vol 263 (2) ◽  
pp. 210-236 ◽  
Author(s):  
P. Doll ◽  
G.J. Wagner ◽  
K.T. Knöpfle ◽  
G. Mairle

2011 ◽  
Vol 309 (1-2) ◽  
pp. 77-88 ◽  
Author(s):  
Clara L. Blättler ◽  
Hugh C. Jenkyns ◽  
Linda M. Reynard ◽  
Gideon M. Henderson

2007 ◽  
Vol 3 (3) ◽  
pp. 729-753 ◽  
Author(s):  
K. Ljung ◽  
S. Björck ◽  
H. Renssen ◽  
D. Hammarlund

Abstract. One of the most distinct climate fluctuations during the Holocene is the short and rapid event centred around 8200 years ago, the 8.2 kyr event, which was most likely triggered by glacial melt-water forcing from the receding Laurentide ice-sheet. Evidence for this cooling has primarily been reported from sites around the North Atlantic, but an increasing number of observations imply a more wide-spread occurrence. Palaeoclimate archives from the Southern Hemisphere have hitherto failed to uncover a distinct climatic anomaly associated with the 8.2 kyr event. Here we present a lake sediment record from Nightingale Island in the central South Atlantic showing enhanced precipitation between 8275 and 8025 cal. yrs BP, most likely as a consequence of increased sea surface temperature (SST). We show that this is consistent with climate model projections of a warming of the South Atlantic in response to reduced north-ward energy transport during the 8.2 kyr event.


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