Experimental isobaric vapour–liquid–liquid equilibrium data for the quaternary systems water (1)–ethanol (2)–acetone (3)–n-butyl acetate (4) and water (1)–ethanol (2)–acetone (3)–methyl ethyl ketone (4) and their partially miscible-constituent ternaries

2007 ◽  
Vol 251 (2) ◽  
pp. 149-160 ◽  
Author(s):  
O.A.D. Younis ◽  
D.W. Pritchard ◽  
M.M. Anwar
Author(s):  
V. I. Zhuchkov ◽  
S. L. Nazansky ◽  
O. N. Krupinova ◽  
A. K. Frolkova

The experimental temperature dependence of the vapour pressures of isobutyl acetate, acetic acid and methyl ethyl ketone were determined, and isobaric vapour-liquid equilibrium data of binary systems of methyl ethyl ketone + isobutyl acetate and methyl ethyl ketone + acetic acid were obtained. The experimental data were processed using the Antoine and Riedel equations and the NRTL and Wilson local composition equations, respectively. Comparison of the experimental and calculated data confirmed the adequacy of the vapour-liquid equilibrium mathematical simulation.


2012 ◽  
Vol 550-553 ◽  
pp. 2616-2620
Author(s):  
Xiao Li ◽  
Yun Ren Qiu

Atmospheric vapor-liquid equilibrium data of methyl ethyl ketone (MEK) - methyl isobutyl ketone (MIBK) were measured using an improved Rose still and were used to recover the parameters of NRTL and UNIQUAC models. The results show that the simulated results agree well with the experimental data. The mean temperature variation is 0.14 °C and the mean mole fraction variation is 0.0023 using UNIQUAC model while the mean temperature variation is 0.17 °C and the mean mole fraction variation is 0.0025 using NRTL model. Both models can be used to calculate the atmospheric vapor-liquid equilibrium data of MEK - MIBK.


Sign in / Sign up

Export Citation Format

Share Document