Measurement and modelling of hydrogen bonding in 1-alkanol+n-alkane binary mixtures

2007 ◽  
Vol 261 (1-2) ◽  
pp. 272-280 ◽  
Author(s):  
Nicolas von Solms ◽  
Lars Jensen ◽  
Jonas L. Kofod ◽  
Michael L. Michelsen ◽  
Georgios M. Kontogeorgis
Keyword(s):  
Hydrogen Bonding ◽  
Binary Mixtures

The effect of introducing an ether group into an imidazolium-based ionic liquid in binary mixtures with DMSO

2020 ◽  
Vol 22 (27) ◽  
pp. 15734-15742 ◽  
Author(s):  
Yu Zhou ◽  
Xianzhen Xu ◽  
Zonghua Wang ◽  
Shida Gong ◽  
Hong Chen ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Hydrogen Bonding ◽  
Dimethyl Sulfoxide ◽  
Binary Mixtures ◽  
Ether Group ◽  
Hydrogen Bonding Interactions

Combined DFT and FTIR investigations reveal interesting hydrogen bonding interactions between dimethyl sulfoxide and an ether-functionalized imidazolium-based ionic liquid.

Excess Volumes and Isentropic Compressibilities of Binary Mixtures of Butylamine and Cyclic Ketones

1979 ◽  
Vol 32 (8) ◽  
pp. 1649 ◽  
Author(s):  
M Sreenivasulu ◽  
PR Naidu
Keyword(s):  
Hydrogen Bonding ◽  
Binary Mixtures ◽  
Isentropic Compressibility ◽  
Excess Volumes ◽  
Cyclic Ketones ◽  
Isentropic Compressibilities ◽  
Deviation In Isentropic Compressibility

Excess volumes and isentropic compressibilities for the binary mixtures of cyclohexanone, cylopentanone and 2-methylcyclohexanone with butylamine were determined at 303�15 and 313�15 K. Excess volumes of the three mixtures are negative over the whole range of compositions at both the temperatures. Deviations in isentropic compressibility are also negative in all the three mixtures. The results are ascribed to strong hydrogen bonding between unlike molecules. The results also suggest that cyclization decreases both √E and the deviation in isentropic compressibility.

The second virial coefficients of mixed organic vapours

1952 ◽  
Vol 210 (1103) ◽  
pp. 557-564 ◽  
Keyword(s):  
Hydrogen Bonding ◽  
Binary Mixtures ◽  
Diethyl Ether ◽  
Virial Coefficient ◽  
Second Virial Coefficient ◽  
Virial Coefficients ◽  
Corresponding States ◽  
Linear Variation ◽  
Second Virial Coefficients

The second virial coefficients of some binary mixtures of organic vapours have been measured at temperatures between 50 and 120° C. Mixtures of n -hexane with chloroform and of n -hexane with diethyl ether show a linear variation of second virial coefficient with composition. This is shown to be in accordance with prediction from the principle of corresponding states. Mixtures of chloroform with diethyl ether show a linear variation at 120° C, but pronounced curvature at lower temperatures. This is interpreted quantitatively as being due to association by hydrogen bonding with an energy of 6020 cal/mole.

Atomistic Insights into Hydrogen-Bonding-Driven Competitive Adsorption of Acetone–Chloroform Binary Mixtures

2019 ◽  
Vol 123 (49) ◽  
pp. 29729-29738 ◽  
Author(s):  
Nityanshu Kumar ◽  
Saranshu Singla ◽  
Michael C. Wilson ◽  
Sukhmanjot Kaur ◽  
Selemon Bekele ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Binary Mixtures ◽  
Competitive Adsorption
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