This work is devoted to the study of the dynamics of combustion wave propagation in oxygen-enriched mixtures of n-heptane with air and jet fuel "Jet A-1" in a small-size pulsed detonation combustor (PDC) with a diameter of 20 mm and a length less than 1 m. Experiments are carried out after the PDC reaches a stationary thermal regime when changing the equivalence ratio (ϕ = 0.73-1.89) and the oxygen-to-air ratio ([O2/air] = 0.15-0.60). The velocity of the combustion wave is determined by measuring the propagation time of the flame front between adjacent pressure sensors that form measurement segements along the PDC.