Effectiveness of non-Fickian diffusion model on the water uptake determination of organic coatings

2020 ◽  
Vol 2020 (2) ◽  
pp. 5
2019 ◽  
Vol 136 ◽  
pp. 105206
Author(s):  
Franky Esteban Bedoya-Lora ◽  
Félix Echeverría ◽  
Jorge Andrés Calderón

2017 ◽  
Vol 112 ◽  
pp. 93-100 ◽  
Author(s):  
Anh Son Nguyen ◽  
Nicolas Causse ◽  
Marco Musiani ◽  
Mark E. Orazem ◽  
Nadine Pébère ◽  
...  

SPE Journal ◽  
2021 ◽  
pp. 1-26
Author(s):  
Ye Tian ◽  
Chi Zhang ◽  
Zhengdong Lei ◽  
Xiaolong Yin ◽  
Hossein Kazemi ◽  
...  

Summary Most simulators currently use the advection/diffusion model (ADM), where the total flux comprises Darcian advection and Fickian diffusion. However, significant errors can arise, especially for modeling diffusion processes in fractured unconventional reservoirs, if diffusion is modeled by the conventional Fick’s law using molar concentration. Hence, we propose an improved multicomponent diffusion model for fractured reservoirs to better quantify the multiphase multicomponent transport across the fracture/matrix interface. We first give a modified formulation of the Maxwell-Stefan (MS) equation to model the multicomponent diffusion driven by the chemical potential gradients. A physics-based modification is proposed for the ADM in fractured reservoirs, where fracture, matrix, and their interface are represented by three different yet interconnected flow domains to honor the flux continuity at the fracture/matrix interface. The added interface using a more representative fluid saturation and composition of the interface can hence better capture the transient mass fluxes between fracture and matrix. The proposed approach is also implemented in an in-house compositional simulator. The multicomponent diffusion model is validated with both intraphase and interphase diffusion experiments. Then, the improved model for fracture/matrix interaction is compared with a fine-grid model. The proposed multiple interacting continua (MINC) model with three continua (MINC3) can better match the fine-grid model’s result than the double-porosity (DP) model, which only obtains a fair match at an early time. Then, we simulate a gas huff ‘n’ puff (HnP) well in the Permian Basin to investigate the effect of diffusion within the fractured tight oil reservoir. The simulation reveals that diffusion has a minor effect on the performance of depletion when oil is the dominant phase. For gas HnP, the simulation neglecting diffusion will underestimate the oil recovery factor (RF) but overestimate the gas rate. The DP approach tends to overestimate the RF of heavy components but leads to a similar cumulative oil RF compared with MINC3. With the diffusion included in the simulation, gas HnP performance becomes more sensitive to the soaking time than the model without diffusion. Although increasing the soaking time will lead to a higher RF after considering diffusion, the incremental oil is not sufficiently large to justify a prolonged soaking time.


Buildings ◽  
2020 ◽  
Vol 10 (1) ◽  
pp. 18 ◽  
Author(s):  
Jeanette Orlowsky ◽  
Franziska Braun ◽  
Melanie Groh

The durability of eleven different water repellents applied on one sandstone type was studied after a long-term weathering at seven different locations in Germany. By measuring colour changes, it could be shown that the formation of black crusts, the deposition of particles and biogenic growth caused a gradual darkening as well as significant changes in total colour over time. Additionally, the water absorption behaviour was investigated with two different methods: applying a low pressure using the pipe method and capillary water absorption measurements from a wet underlay. Afterwards, the test results were analysed with four different evaluation methods: calculation of the protection degree from pipe method and capillary water absorption, determination of the velocity of water uptake during capillary water absorption and calculation of the damaged depth of the stone surface using single-sided NMR technique. The growing damaged depth leads to an increase of the water uptake velocity and to a decrease of the protection degree of the applied hydrophobing agents. Three protective agents based on isobutyltrimethoxysilane showed already after two years of outdoor weathering a clear loss of performance, which significantly increased after 30 years of exposure.


1983 ◽  
Vol 2 (4) ◽  
pp. 289-299 ◽  
Author(s):  
R.M.V.G.K. Rao ◽  
Manas Chanda ◽  
N. Balasubramanian

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