Equilibrium vs. kinetic fractionation of oxygen isotopes in two low-temperature travertine-depositing systems with differing hydrodynamic conditions at Baishuitai, Yunnan, SW China

2012 ◽  
Vol 95 ◽  
pp. 63-78 ◽  
Author(s):  
Hao Yan ◽  
Hailong Sun ◽  
Zaihua Liu
Lithos ◽  
2019 ◽  
Vol 324-325 ◽  
pp. 418-428 ◽  
Author(s):  
Maohong Chen ◽  
Leon Bagas ◽  
Xin Liao ◽  
Zhiqiang Zhang ◽  
Qiuli Li
Keyword(s):  

2020 ◽  
Vol 280 ◽  
pp. 395-422 ◽  
Author(s):  
Ziv Sade ◽  
Ruth Yam ◽  
Aldo Shemesh ◽  
Itay Halevy

2021 ◽  
Vol 2021 ◽  
pp. 1-10
Author(s):  
Mengnan Zhang ◽  
Xiaoqian Li ◽  
Xuxue Cheng ◽  
Xinfeng Wang ◽  
Mian Song ◽  
...  

Perchlorate (ClO4−) is an emerging persistent pollutant that is ubiquitous in the environment at trace concentrations. Perchlorate ingestion poses a risk to human health because it interferes with thyroidal hormone production. The identification of perchlorate sources in groundwater is a primary concern. Chlorine and multi-oxygen isotopic tracing of perchlorate (δ37Cl, 36Cl/Cl, δ18O, and Δ17O) can provide a unique tool for identifying the origin and transport of perchlorate in groundwater. Along with the kinetic fractionation of chlorine and oxygen isotopes, the Δ17O value, 36Cl/Cl ratio, and ε18O/ε37Cl (the fractionation coefficient of oxygen and chlorine isotopes) are constant, potentially indicating the biodegradation of perchlorate, without disguising its source information. Therefore, comprehensive characterization of stable chlorine and poly-oxygen isotopes is expected to provide direct evidence for identifying the source of perchlorate in groundwater. However, further studies are needed to increase the amount of isotopic data of different perchlorate sources, to make the end-member model available to broader regions. It is critically important to understand the range of values and differences of isotopes among natural perchlorate sources and the perchlorate formation mechanisms.


1988 ◽  
Vol 70 (1-2) ◽  
pp. 185 ◽  
Author(s):  
L.D. Labeyrie ◽  
A. Juillet-Leclerc ◽  
P. Binz ◽  
A. Decarreau

2018 ◽  
Vol 3 (2) ◽  
pp. 233-239 ◽  
Author(s):  
Hagar Lis ◽  
Tal Weiner ◽  
Frances D. Pitt ◽  
Nir Keren ◽  
Alon Angert

2021 ◽  
Vol 9 ◽  
Author(s):  
Yanyan Li ◽  
Ji Dor ◽  
Chengjiang Zhang ◽  
Guiling Wang ◽  
Baojian Zhang ◽  
...  

The Xifeng geothermal field is located in the Yangtze Craton, SW China, and is one of the most representative low-temperature geothermal fields in China. Widespread thermal anomalies, hot springs, and geothermal wells have been reported by previous studies. However, the nature and forming mechanisms of the field remain poorly understood. Element geochemical (ions, rare earth elements) and stable isotopic (D, O) composition of hot springs, geothermal fluids, rivers, and cold springs from different locations of the Xifeng geothermal field were analyzed in this study. The ions studies revealed that most samples featured the Ca-Mg-HCO3 type, except Xifeng hot springs, and which were characterized by the Ca-Mg-HCO3-SO4 type. Based on quartz geothermometers, the estimated reservoir temperature was 77°C. The results of stable isotopes (D, O) manifest that the Xifeng geothermal system was recharged by meteoric water at an elevation of 1,583 m from SW to NE. The research of rare earth elements (REE) revealed that their accumulation characteristics and obvious positive Eu anomaly were inherited from host feldspar-bearing reservoir dolomites through water-rock interactions. Combined with these observations, geological setting, and previous studies, it was concluded that the formation of the Xifeng geothermal field resulted from recharge, deep circulation, and secondary rising of the meteoric water along the faults. First, meteoric water infiltrated to depth through faults and crack zones. Second, the deep-infiltrated water was heated by radioactive heat, deep heat, and tectonic frictional heat. Finally, as the warmed-up waters underwent considerable deep circulation in the reservoir, it rose again along the main faults, and mixed with groundwater near the surface. Taken together, we suggest that the Xifeng geothermal system should be assigned as a faults-controlling, and deeply circulating meteoric water of low-temperature category.


1993 ◽  
Vol 73 (4) ◽  
pp. 633-637 ◽  
Author(s):  
J. J. Miller ◽  
G. J. Beke ◽  
S. Pawluk ◽  
H. R. Krouse

Possible sources of SO4 in soil, drift and bedrock at two saline sites in southern Alberta were investigated using sulfur and oxygen isotope analyses. Slight differences (0.6–5.2 per mil) between δ34S values of SO4 and insoluble S in the geologic material were attributed to kinetic fractionation during oxidation of organic S. Negative δ18O values of SO4 in the shallow (<6 m) bedrock, drift and soil reflected oxidation of reduced S. In contrast, positive δ18O values in the deep (>6 m) bedrock indicated sulfate reduction. The exact source of SO4 could not be determined in this preliminary study. The isotope approach, however, shows promise and warrants more detailed study. Key words: Salinization, sulfates, sulfur isotopes, oxygen isotopes


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