CALCITE U-Pb DATING UNRAVELS THE AGE AND HYDROTHERMAL HISTORY OF THE GIANT SHUIYINDONG CARLIN-TYPE GOLD DEPOSIT IN THE GOLDEN TRIANGLE, SOUTH CHINA

The ages of Carlin-type gold deposits in the Golden Triangle of South China have long been questioned due to the general lack of minerals unequivocally linked to gold deposition that can be precisely dated using conventional radiogenic isotope techniques. Recent advances in U-Pb methods show that calcite can be used to constrain the ages of hydrothermal processes, but few studies have been applied to ore deposits. Herein, we show that this approach can be used to constrain the timing of hydrothermal activity that generated and overprinted the giant Shuiyindong Carlin-type gold deposit in the Golden Triangle. Three stages of calcite (Cal-1, Cal-2, and Cal-3) have been recognized in this deposit based on crosscutting relationships, cathodoluminescence colors, and chemical (U, Pb, and rare earth element [REE]) and isotope (C, O, Sr) compositions. Cal-1 is texturally associated with ore-stage jasperoid and disseminated Au-bearing arsenian pyrite in hydrothermally altered carbonate rocks, which suggests it is synmineralization. Cal-2 fills open spaces and has a distinct orange cathodoluminescence, suggesting that it precipitated during a second fluid pulse. Cal-1 and Cal-2 have similar carbonate rock-buffered chemical and isotopic compositions. Cal-3 occurs in veins that often contain realgar and/or orpiment and are chemically (low U, Pb, and REE) and isotopically (higher δ13C, lower δ18O and Sri values) distinct from Cal-1 and Cal-2, suggesting that it formed from a third fluid. U-Pb isotope analyses, by laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) for U-rich Cal-1 and Cal-2 and by LA-multicollector (MC)-ICP-MS for U-poor Cal-3, yield well-defined age constraints of 204.3 to 202.6, 191.9, and 139.3 to 137.1 Ma for Cal-1, Cal-2, and Cal-3, respectively. These new ages suggest that the Shuiyindong gold deposit formed in the late Triassic and was overprinted by hydrothermal events in the early Jurassic and early Cretaceous. Given the association of Cal-3 with orpiment and realgar, and previous geochronologic studies of several other major gold deposits in the Golden Triangle, we infer that the latest stage of calcite may be associated with an early Cretaceous regional gold metallogenic event. Combined with existing isotopic ages in the region, these new ages lead us to propose that Carlin-type gold deposits in the Golden Triangle formed during two metallogenic episodes in extensional settings, associated with the late Triassic Indochina orogeny and early Cretaceous paleo-Pacific plate subduction. This study shows that the calcite U-Pb method can be used to constrain the timing of Carlin-type gold deposits and successive hydrothermal events.

U-Pb Dating on Hydrothermal Rutile and Monazite from the Badu Gold Deposit Supports an Early Cretaceous Age for Carlin-Type Gold Mineralization in the Youjiang Basin, Southwestern China

The Youjiang basin on the southwestern margin of the Yangtze block in southwestern China is the world’s second largest Carlin-type gold province after Nevada, USA. The lack of precise age determinations on gold deposits in this province has hindered understanding of their genesis and relation to the geodynamic setting. Although most Carlin-type gold deposits in the basin are hosted in calcareous sedimentary rocks, ~70% of the ore in the Badu Carlin-type gold deposit is hosted by altered and sulfidized dolerite. Although in most respects Badu is similar to other Carlin-type gold deposits in the province, alteration of the unusual dolerite host produced hydrothermal rutile and monazite that can be dated. Field observations show that gold mineralization is spatially associated with, but temporally later than, dolerite. In situ secondary ion mass spectrometry (SIMS) U-Pb dating on magmatic zircon from the least altered dolerite yielded a robust emplacement age of 212.2 ± 1.9 Ma (2σ, mean square of weighted deviates [MSWD] = 0.55), providing a maximum age constraint on gold mineralization. The U-Th/He ages of detrital zircons from hydrothermally mineralized sedimentary host rocks at Badu and four other Carlin-type gold deposits yielded consistent weighted mean ages of 146 to 130 Ma that record cooling from a temperature over 180° to 200°C and place a lower limit on the age of gold mineralization in the basin. Hydrothermal rutile and monazite that are coeval with gold mineralization have been identified in the mineralized dolerite. Rutile is closely associated with hydrothermal ankerite, sericite, and gold-bearing pyrite. It has high concentrations of W, Fe, V, Cr, and Nb, as well as growth zones that are variably enriched in W, Fe, Nb, and U. Monazite contains primary two-phase fluid inclusions and is intergrown with gold-bearing pyrite and hydrothermal minerals. In situ SIMS U-Pb dating of rutile yielded a Tera-Wasserburg lower intercept age of 141.7 ± 5.8 Ma (2σ, MSWD = 1.04) that is within error of the in situ SIMS Th-Pb age of 143.5 ± 1.4 Ma (2σ, MSWD = 1.5) on monazite. These ages are ~70 m.y. younger than magmatic zircons in the host dolerite and are similar to the aforementioned U-Th/He cooling ages on detrital zircons from hydrothermally mineralized sedimentary host rocks. We, therefore, conclude that the Badu Carlin-type gold deposit formed at ca. 144 Ma. The agreement of the rutile and monazite ages with the U-Th-He cooling ages of Badu and four other Carlin-type gold deposits in the Youjiang basin suggests that ca. 144 Ma is representative of a regional Early Cretaceous Carlin-type hydrothermal event formed during back-arc extension.

NOBLE GASES FINGERPRINT THE SOURCE AND EVOLUTION OF ORE-FORMING FLUIDS OF CARLIN-TYPE GOLD DEPOSITS IN THE GOLDEN TRIANGLE, SOUTH CHINA

Precise constraints on the source and evolution of ore-forming fluids of Carlin-type gold deposits in the Golden Triangle (south China) are of critical importance for a better understanding of the ore genesis and a refined genetic model for gold mineralization. However, constraints on the source of ore fluid components have long been a challenge due to the very fine grained nature of the ore and gangue minerals in the deposits. Here we present He, Ne, and Ar isotope data of fluid inclusion extracts from a variety of ore and gangue minerals (arsenian pyrite, realgar, quartz, calcite, and fluorite) representing the main and late ore stages of three well-characterized major gold deposits (Shuiyindong, Nibao, and Yata) to provide significant new insights into the source and evolution of ore-forming fluids of this important gold province. Measured He isotopes have R/RA ratios ranging from 0.01 to 0.4 that suggest a maximum of 5% mantle helium with an R/RA of 8. The Ne and Ar isotope compositions are broadly comparable to air-saturated water, with a few analyses indicating the presence of an external fluid containing nucleogenic 38Ar and radiogenic 40Ar. Plotted on the 20Ne/4He vs. helium R/RA and 3He/20Ne vs. 4He/20Ne diagrams, the results define two distinct arrays that emanate from a common sedimentary pore fluid or deeply sourced metamorphic fluid end-member containing crustal He. The main ore-stage fluids are interpreted as a mixture of magmatic fluid containing mantle He and sedimentary pore fluid or deeply sourced metamorphic fluid with predominantly crustal He, whereas the late ore-stage fluids are a mixture of sedimentary pore fluid or deeply sourced metamorphic fluid bearing crustal He and shallow meteoric groundwater containing atmospheric He. Results presented here, when combined with independent evidence, support a magmatic origin for the ore-forming fluids. The ascending magmatic fluid mixed with sedimentary pore fluid or deeply sourced metamorphic fluid in the ore stage and subsequently mixed with the meteoric groundwater in the late ore stage, eventually producing the Carlin-type gold deposits in the Golden Triangle.

Chapter 36: Carlin-Type Gold Deposits in Nevada: Geologic Characteristics, Critical Processes, and Exploration

Carlin-type gold deposits in Nevada account for ~5% of worldwide annual gold production, typically about ~135 metric tons (t) (~4.5 Moz) per year. They are hydrothermal epigenetic replacement bodies hosted predominantly in carbonate-bearing sedimentary rocks. They are known for their “invisible” gold that occurs in the crystal structure of pyrite. Over 95% of the production from these deposits is from four clusters of deposits, which include the Carlin trend and the Cortez, Getchell, and Jerritt Canyon camps. Despite differences in the local geologic settings, the characteristics of the deposits are very similar in the four clusters. Shared characteristics include: (1) alteration characterized by carbonate dissolution, silicate argillization, and silicification; (2) ore formation characterized by auriferous arsensian pyrite, typically as rims on preore pyrite, followed by late open-space deposition of orpiment, realgar, stibnite, and other minerals; (3) Ag/Au ratios of <1 in ore; (4) an As-Hg-Sb-Tl geochemical signature; (5) low temperatures (~160°–240°C) and salinities of ore fluids (~1–6 wt % NaCl equiv) and fairly shallow depths of formation (<~2–3 km); and (6) lack of mineral and elemental zoning around ore. The four clusters share regional geologic controls related to formation as follows: (1) along the rifted margin of a craton, (2) within the slope facies of a passive margin sequence dominated by carbonates, (3) in the lower plate of a regional thrust fault, and (4) during a narrow time interval in the late Eocene (~42–34 Ma). The geometries and ore controls of the deposits in the four clusters are also very similar. At the deposit scale, ore and hydrothermal alteration are commonly associated with high-angle faults and preore low-angle contractional structures, including thrust faults and folds. The high-angle faults acted as fluid pathways for upwelling ore fluids, which were then diverted into lower angle favorable strata and contractional structures, where fluid-rock interaction led to replacement of carbonate and formation of ore. Rheologic contrasts between lithologies were also critical in diverting fluids into wall rocks. Common rheologic contrasts include contacts between thin- and thick-bedded lithologic units and the margins of contact metamorphic aureoles associated with Mesozoic intrusions. The similarities suggest common processes. Four critical processes are apparent: (1) development of source(s) for gold and other critical components of the ore fluids, (2) formation of fluid pathways, (3) water-rock interaction and gold deposition, and (4) a tectonic trigger, which was renewal of magmatism and a change from contraction to extension in the late Eocene. Consensus exists on these processes, except for the source of gold and other components of the ore fluid, with most models calling upon either a magmatic-hydrothermal source or a crustal source, where metals were scavenged by either meteoric or metamorphic fluids. Future research should focus on Carlin-style deposits in Nevada that exhibit epithermal characteristics and deposits that appear to have a clear genetic association with magmatic-hydrothermal systems associated with upper crustal intrusions. Rather than discrete types of ore deposits, there may be continua between Carlin-type gold deposits, epithermal deposits, and distal disseminated deposits, with the four large camps representing an end member.

Chapter 16: Giant Carlin-Type Gold Deposits of the Cortez District, Lander and Eureka Counties, Nevada

The Cortez district is in one of the four major Carlin-type gold deposit trends in the Great Basin province of Nevada and contains three giant (>10 Moz) gold orebodies: Pipeline, Cortez Hills, and Goldrush, including the recently discovered Fourmile extension of the Goldrush deposit. The district has produced >21 Moz (653 t) of gold and contains an additional 26 Moz (809 t) in reserves and resources. The Carlin-type deposits occur in two large structural windows (Gold Acres and Cortez) of Ordovician through Devonian shelf- and slope-facies carbonate rocks exposed through deformed, time-equivalent lower Paleozoic siliciclastic rocks of the overlying Roberts Mountains thrust plate. Juxtaposition of these contrasting Paleozoic strata occurred during the late Paleozoic Antler orogeny along the Roberts Mountains thrust. Both upper and lower plate sequences were further deformed by Mesozoic compressional events. Regional extension, commencing in the Eocene, opened high- and low-angle structural conduits for mineralizing solutions and resulted in gold deposition in reactive carbonate units in structural traps, including antiforms and fault-propagated folds. The Pipeline and Cortez Hills deposits are located adjacent to the Cretaceous Gold Acres and Jurassic Mill Canyon granodioritic stocks, respectively; although these stocks are genetically unrelated to the later Carlin-type mineralization event, their thermal metamorphic aureoles may have influenced ground preparation for later gold deposition. Widespread decarbonatization, argillization, and silicification of the carbonate host rocks accompanied gold mineralization, with gold precipitated within As-rich rims on fine-grained pyrite. Pipeline and Cortez Hills also display deep supergene oxidation of the hypogene sulfide mineralization. Carlin-type mineralization in the district is believed to have been initiated in the late Eocene (>35 Ma) based on the age of late- to postmineral rhyolite dikes at Cortez Hills. The Carlin-type gold deposits in the district share common structural, stratigraphic, alteration, and ore mineralogic characteristics that reflect common modes of orebody formation. Ore-forming fluids were channeled along both low-angle structures (Pipeline, Goldrush/Fourmile) and high-angle features (Cortez Hills), and gold mineralization was deposited in Late Ordovician through Devonian limestone, limy mudstone, and calcareous siltstone. The Carlin-type gold fluids are interpreted to be low-salinity (2–3 wt % NaCl equiv), low-temperature (220°–270°C), and weakly acidic, analogous to those in other Carlin-type gold deposits in the Great Basin. The observed characteristics of the Cortez Carlin-type gold deposits are consistent with the recently proposed deep magmatic genetic model. Although the deposits occur over a wide geographic area in the district, it is possible that they initially formed in greater proximity to each other and were then spatially separated during Miocene and post-Miocene regional extension.

A Nanoscale Investigation of Carlin-Type Gold Deposits: An Atom-Scale Elemental and Isotopic Perspective

Carlin-type gold deposits are one of the most important gold mineralization styles in the world. Despite their economic importance and the large volume of work that has been published, there remain crucial questions regarding their metallogenesis. Much of this uncertainty is due to the cryptic nature of the gold occurrence, with gold occurring as dispersed nanoscale inclusions within host pyrite rims that formed on earlier formed barren pyrite cores. The small size of the gold inclusions has made determining their nature within the host sulfides and the mechanisms by which they precipitated from the ore fluids particularly problematic. This study combines high-resolution electron probe microanalysis (EPMA) with atom probe tomography (APT) to constrain whether the gold occurs as nanospheres or is dispersed within the Carlin pyrites. APT offers the unique capability of obtaining major, minor, trace, and isotopic chemical information at near-atomic spatial resolution. We use this capability to investigate the atomic-scale distribution of trace elements within Carlin-type pyrite rims, as well as the relative differences of sulfur isotopes within the rim and core of gold-hosting pyrite. We show that gold within a sample from the Turquoise Ridge deposit (Nevada) occurs within arsenian pyrite overgrowth (rims) that formed on a pyrite core. Furthermore, this As-rich rim does not contain nanonuggets of gold and instead contains dispersed lattice-bound Au within the pyrite crystal structure. The spatial correlation of gold and arsenic within our samples is consistent with increased local arsenic concentrations that enhanced the ability of arsenian pyrite to host dispersed gold (Kusebauch et al., 2019). We hypothesize that point defects in the lattice induced by the addition of arsenic to the pyrite structure facilitate the dissemination of gold. The lack of gold nanospheres in our study is consistent with previous work showing that dispersed gold in arsenian pyrite can occur in concentrations up to ~1:200 (gold/arsenic). We also report a method for determining the sulfur isotope ratios from atom probe data sets of pyrite (±As) that illustrates a relative change between the pyrite core and its Au and arsenian pyrite rim. This spatial variation confirms that the observed pyrite core-rim structure is due to two-stage growth involving a sedimentary or magmatic-hydrothermal core and hydrothermal rim, as opposed to precipitation from an evolving hydrothermal fluid.