Leaching of rare earth elements from waste lamp phosphor mixtures by reduced alkali fusion followed by acid leaching

2016 ◽  
Vol 163 ◽  
pp. 99-103 ◽  
Author(s):  
Yong Liang ◽  
Yuanxin Liu ◽  
Rudan Lin ◽  
Doudou Guo ◽  
Chunfa Liao
2018 ◽  
Vol 15 (3) ◽  
Author(s):  
Parul Johar ◽  
Vishal Jangir ◽  
Yogita Choudhary ◽  
Sudhanshu Mallick

Modern fluorescent lamp phosphor powder contains tricolor phosphor. This tricolor phosphor consists of three different types of rare earth phosphors: red (YOX), green (CMAT/LAP) and blue (BAM); mixed in varying proportions. The exact separation of these three rare earth phosphors is essential in order to precisely recover the contained rare earth elements from waste lamps phosphor. In this present work, we reported an efficient methodology for the separation of these three tricolor phosphors and the selective extraction of predominantly presented red phosphor (YOX) constituents using acid leaching. The waste phosphor powder was leached with different acids: both organic and inorganic type. The 3 M H2SO4 leaching was found to be most suitable for the selective extraction of red phosphor constituents, i.e. Y and Eu. The recovered phosphor powder was analyzed with SEM/EDS and XRD analysis. The obtained XRD pattern was refined using Rietveld refinement method for the quantification of phases present. Recovered red phosphor powder contained three main crystalline phases Y2O3, Eu2O3 and Y2OS2. KEYWORDS: Waste Lamp Phosphor; Tricolor Phosphor; Rare Earth Elements; Acid Leaching


2013 ◽  
Vol 788 ◽  
pp. 279-282 ◽  
Author(s):  
Yu Feng Wu ◽  
Rui Qing Li ◽  
Qi Jun Zhang ◽  
Wei Wang

Two methods, direct acid leaching, alkali fusion and acid leaching, were adopted to deal with the Waste Trichromatic Fluorescent Phosphors (WTFPs). The research results showed that using the direct acid leaching method can only dissolved the Red phosphors. And yet, high-temperature alkali fusion could effectively destroy the Mg-Al spinel structure of the components of the Blue and the Green phosphors, and make REEs dissolved completely. The acid leaching efficiency of REEs could reach 100% when the weight ratio of NaOH with WTFPs is 6:1, and the calcination temperature is 900 °C and the reaction time is 4 hrs.


2019 ◽  
Vol 136 ◽  
pp. 36-42 ◽  
Author(s):  
Mengcheng Tang ◽  
Changchun Zhou ◽  
Jinhe Pan ◽  
Ningning Zhang ◽  
Cheng Liu ◽  
...  

2016 ◽  
Vol 166 ◽  
pp. 195-204 ◽  
Author(s):  
Mugdha Walawalkar ◽  
Connie K. Nichol ◽  
Gisele Azimi

JOM ◽  
2019 ◽  
Vol 71 (12) ◽  
pp. 4578-4587 ◽  
Author(s):  
Seyed Ramin Banihashemi ◽  
Bijan Taheri ◽  
Seyed Mohammad Razavian ◽  
Faraz Soltani

Minerals ◽  
2016 ◽  
Vol 6 (3) ◽  
pp. 63 ◽  
Author(s):  
Rina Kim ◽  
Heechan Cho ◽  
Kenneth Han ◽  
Kihong Kim ◽  
Myoungwook Mun

2022 ◽  
Vol 175 ◽  
pp. 107278
Author(s):  
Bin Ji ◽  
Qi Li ◽  
Rick Honaker ◽  
Wencai Zhang

2020 ◽  
Vol 11 (4) ◽  
pp. 804
Author(s):  
Iga Trisnawati ◽  
Gyan Prameswara ◽  
Panut Mulyono ◽  
Agus Prasetya ◽  
Himawan Tri Bayu Murti Petrus

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