Chalcopyrite leaching with iodine (JX Iodine Process) for various ore types

2021 ◽  
pp. 105752
Author(s):  
Yuken Fukano ◽  
Akira Miura
Keyword(s):  
2018 ◽  
Vol 82 (S1) ◽  
pp. S5-S41 ◽  
Author(s):  
J. R. S. Carvalho ◽  
J. M. R. S. Relvas ◽  
A. M. M. Pinto ◽  
M. Frenzel ◽  
J. Krause ◽  
...  

ABSTRACTHigh concentrations of indium (In) and selenium (Se) have been reported in the Neves-Corvo volcanic-hosted massive sulfide deposit, Portugal. The distribution of these ore metals in the deposit is complex as a result of the combined effects of early ore-forming processes and late tectonometamorphic remobilization. The In and Se contents are higher in Cu-rich ore types, and lower in Zn-rich ore types. At the deposit scale, both In and Se correlate positively with Cu, whereas their correlations with Zn are close to zero. This argues for a genetic connection between Cu, In and Se in terms of metal sourcing and precipitation. However, re-distribution and re-concentration of In and Se associated with tectonometamorphic deformation are also processes of major importance for the actual distribution of these metals throughout the whole deposit. Although minor roquesite and other In-bearing phases were recognized, it is clear that most In within the deposit is found incorporated within sphalerite and chalcopyrite. When chalcopyrite and sphalerite coexist, the In content in sphalerite (avg. 1400 ppm) is, on average, 2–3 times higher than in chalcopyrite (avg. 660 ppm). The In content in stannite (avg. 1.3 wt.%) is even higher than in sphalerite, but the overall abundance of stannite is subordinate to either sphalerite or chalcopyrite. Selenium is dispersed widely between many different ore minerals, but galena is the main Se-carrier. On average, the Se content in galena is ~50 times greater than in either chalcopyrite (avg. 610 ppm) or sphalerite (avg. 590 ppm). The copper concentrate produced at Neves-Corvo contains very significant In (+Se) content, well above economic values if the copper smelters recovered it. Moreover, the high In content of sphalerite from some Cu-Zn ores, or associated with shear structures, could possibly justify, in the future, a selective exploitation strategy for the production of an In-rich zinc concentrate.


2021 ◽  
Vol 192 ◽  
pp. 22
Author(s):  
Thomas Poitrenaud ◽  
Éric Marcoux ◽  
Romain Augier ◽  
Marc Poujol

A field study combined with a laboratory study and 3D modeling have been performed in order to decipher the genesis of the Salau deposit W-Au mineralization (Pyrenees, France), one of the most important for tungsten in Europe. Results show the existence of two superimposed ore types, emplaced ca. 10 km depth and within decreasing temperature conditions: a calcic silicates skarn with rare scheelite and disseminated sulphides followed by a mineralized breccia with massive sulphides (pyrrhotite and chalcopyrite dominant), coarse-grained scheelite and gold, representing the main part of the ore mined in the past. This breccia is localized in ductile-brittle shear-zones which crosscut the granodiorite. U/Pb dating on zircon, apatite and scheelite, previously realized, confirmed this polyphase evolution. These two types of mineralization, linked to the emplacement of two successive intrusions as confirmed by sulphur isotopic analysis, granodioritic then leucogranitic, can be classified as belonging to the Intrusion-Related Gold Deposit type (IRGD). The emplacement of the high-grade gold and scheelite breccia was initiated by the progressive localization of the regional deformation in the Axial Zone of the Pyrenees during the Permian within E-W dextral-reverse faults.


2021 ◽  
pp. 63-73
Author(s):  
IRINA GABLINA

Based on long-term studies of cupriferous sandstone and shale deposits, as well as deepsea sulfide ores, various types of geochemical barriers where sulfides form are shown. Cupriferous sandstones and shales form as metals precipitate from redbed reservoir waters on H2S geochemical barrier. Syngenetic and epigenetic barrier types are identified. Oceanic sulfide ores from the Central Atlantic region were studied; as a result, a new hydrothermal-metasomatic sediment-hosted mineralization type was found, along with previously known sulfide ore types (massive ores on the seafloor and stockwork ores in substrate rocks). Geochemical seafloor sulfide formation environments and those in biogenic carbonate bottom sediments are examined.


Minerals ◽  
2020 ◽  
Vol 10 (8) ◽  
pp. 716 ◽  
Author(s):  
Alexander E. Marfin ◽  
Alexei V. Ivanov ◽  
Vera D. Abramova ◽  
Tatiana N. Anziferova ◽  
Tatiana A. Radomskaya ◽  
...  

The Oktyabrsk PGE-Cu-Ni deposit is one of the largest resources in the Norilsk–Talnakh ore district, Russia, and it is viewed as an ore giant on a global scale. It contains three types of ores: massive, disseminated and veinlet-disseminated. The two former ore types were formed by a liquation process, whereas the latter was associated with fluid-induced selective metasomatic replacement of metamorphosed wall rocks. One of the major ore minerals in all ore types is chalcopyrite. In this study, we determined concentrations of trace elements in this mineral using laser ablation inductively coupled plasma mass spectrometry. It appeared that standard geochemical tools, such as plotting the data in the form of diagrams of normalized concentrations, binary and ternary plots, do not allow one to distinguish chalcopyrite from visually and genetically different ore types. In contrast, more advanced statistical methods such as cluster analysis show different groupings of elements for each ore type. Based on the element clustering, a classification tree was suggested, which allowed for the differentiation of massive, disseminated and veinlet-disseminated ore types of the Oktyabrsk deposit by Se, Te, Cd and Pb concentrations in chalcopyrite with a success rate of 86%. The general feature is that chalcopyrite of veinlet-disseminated ore is poorer in these elements compared to chalcopyrite of the two other ore types. Chalcopyrite of massive ore is poorer in Se and Te when compared to chalcopyrite of disseminated ore.


2019 ◽  
Vol 114 (8) ◽  
pp. 1481-1494 ◽  
Author(s):  
Curtis L. Johnson ◽  
David A. Browning ◽  
Neil E. Pendock

Abstract The Phoenix mine and predecessor operations in north-central Nevada have produced an aggregate of 5.2 Moz of gold and 550 million pounds of copper from an Eocene-aged Au-Cu porphyry-related skarn. The complex skarn mineralogy intimately associated with ore-grade mineralization poses significant challenges to blasting, mining, comminution, and process operations. These challenges are rooted in highly variable silicate mineralogy, which manifests as fine-grained, submillimeter grain-size, generally green colored rocks that inhibit accurate identification in the field. Prior to this study, all mineralogical data utilized in Phoenix mine ore control were sourced from blast hole cuttings mapped by ore control geologists in the field—the standard practice at many modern mine sites. At Phoenix, a direct link between mineralogy and mill performance was recognized; however, mineralogical data captured in the field was not sufficient to optimize process operations. To address this, it was determined that analytical work was necessary to quantify fine-grained mineralogy of variable ore types. A visible-near and short-wave infrared (VNIR-SWIR) hyperspectral imaging system provided the ideal tool, as it allows near real-time mineralogical data acquisition and semiquantitative determination of mineral abundances. Multiple iterative studies were conducted to prove that hyperspectral imaging of Phoenix ore types provides results suitable for process optimization. This six-month study described here included hyperspectral imaging of 3,008 blast hole cuttings samples from three pits, and 877 crusher feed, rougher feed, and rougher tails samples. Hyperspectral feature extractions derived from mill samples were paired with associated mill performance data and used to build predictive Au-Cu recovery, grade, and throughput models using multiple linear regression, partial least squares, and deep learning techniques with R-correlation values to observed data of 0.56 to 0.71. Blast hole hyperspectral data were then applied to recovery, grade, and throughput models to calculate predicted recoveries and throughputs that were spatially kriged with excellent correlations to geologic features. The application of VNIR-SWIR hyperspectral imaging to blast hole cuttings is a powerful predictive and diagnostic geometallurgical tool in operations where silicate mineralogy has a strong impact on process operations.


1971 ◽  
Vol 38 (294) ◽  
pp. 235-244 ◽  
Author(s):  
E. Z. Basta ◽  
W. S. Saleeb

SummaryThe manganese ores of Elba, South-eastern Desert, occur as numerous veins located within a narrow belt trending N.W.-S.E. Three ore-types were distinguished: hard crystalline ore consisting mainly of pyrolusite or ramsdellite or both, banded colloform ore consisting mainly of psilomelane, and in places cryptomelane, and soft nodular ore consisting of todorokite with minor amounts of psilomelane (or cryptomelane), nsutite, and pyrolusite. Black calcite and baryte occur in some of the veins and increase with depth.Based on the field and mineralogical evidence the origin of the ore is discussed. It is suggested that the ore is a very low-temperature epithermal fissure deposit of black calcite type that occurs near the surface (oxidation zone) in brecciated zones along faults.


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