In situ oxidation triggered heteroleptically deprotonated cobalt(III) and homoleptic nickel(II) complexes of diacetyl monoxime derived tri-nitrogen chelators; Synthesis, molecular structures and biological assay

2017 ◽  
Vol 466 ◽  
pp. 625-631 ◽  
Author(s):  
Vinayak Kamat ◽  
Avinash Kotian ◽  
Anupama Nevrekar ◽  
Krishna Naik ◽  
Dhoolesh Kokare ◽  
...  
Keyword(s):  
Molecular Structures ◽  
Biological Assay ◽  
In Situ Oxidation ◽  
Diacetyl Monoxime

Technology Status Review In Situ Oxidation

1999 ◽  
Author(s):  
VIRGINIA UNIV CHARLOTTESVILLE
Keyword(s):  
In Situ Oxidation

Laccase-Mediated In Situ Oxidation of Dopamine for Dyeing of Human Hair

2021 ◽  
Vol 22 (1) ◽  
pp. 141-148
Author(s):  
Weini Jia ◽  
Shirong Li ◽  
Zhengxin Luo ◽  
Hainan Yu ◽  
Wenjun Zhu ◽  
...  
Keyword(s):  
Human Hair ◽  
In Situ Oxidation

Electronic spectroscopy of iron alloys in the process of in-situ oxidation

2000 ◽  
Vol 36 (3) ◽  
pp. 406-411
Author(s):  
M. G. Nakhodkin ◽  
V. M. Lysenko ◽  
I. P. Koval ◽  
O. F. Bardamyd
Keyword(s):  
Electronic Spectroscopy ◽  
Iron Alloys ◽  
In Situ Oxidation

scholarly journals Thermodynamically stable [4 + 2] cycloadducts of lanthanum-encapsulated endohedral metallofullerenes

2014 ◽  
Vol 10 ◽  
pp. 714-721 ◽  
Author(s):  
Yuta Takano ◽  
Yuki Nagashima ◽  
M Ángeles Herranz ◽  
Nazario Martín ◽  
Takeshi Akasaka
Keyword(s):  
Thermal Stability ◽  
Material Science ◽  
Molecular Structures ◽  
Spectroscopic Methods ◽  
Dynamic Nmr ◽  
The Novel ◽  
Endohedral Metallofullerenes ◽  
Derivatives Of ◽  
Paramagnetic Properties

The [4 + 2] cycloaddition of o-quinodimethanes, generated in situ from the sultine 4,5-benzo-3,6-dihydro-1,2-oxathiin 2-oxide and its derivative, to La metal-encapsulated fullerenes, La2@C80 or La@C82, afforded the novel derivatives of endohedral metallofullerenes (3a,b, 4a,b and 5b). Molecular structures of the resulting compounds were elucidated using spectroscopic methods such as MALDI–TOF mass, optical absorption, and NMR spectroscopy. The [4 + 2] adducts of La2@C80 (3a,b, and 4a,b) and La@C82 (5b), respectively, retain diamagnetic and paramagnetic properties, as confirmed by EPR spectroscopy. Dynamic NMR measurements of 4a at various temperatures demonstrated the boat-to-boat inversions of the addend. In addition, 5b revealed remarkable thermal stability in comparison with the reported [4 + 2] cycloadduct of pentamethylcyclopentadiene and La@C82 (6). These findings demonstrate the utility of sultines to afford thermodynamically stable endohedral metallofullerene derivatives for the use in material science.

scholarly journals A method for pet mechanical properties enhancement

2019 ◽  
Vol 10 (8) ◽  
pp. 1725
Author(s):  
Raffaella Aversa ◽  
Relly Victoria Virgil Petrescu ◽  
Antonio Apicella ◽  
Florian Ion Tiberiu Petrescu
Keyword(s):  
Mechanical Properties ◽  
Liquid Crystalline ◽  
Liquid Crystalline Polymers ◽  
Molecular Structures ◽  
Reactive Blending ◽  
Scanning Calorimetry ◽  
Shear Transfer ◽  
Crystalline Polymers ◽  
Reactive Compatibilizer

A method for PET mechanical properties enhancement by reactive blending with HBA/HNA Liquid Crystalline Polymers for in situ highly fibrillar composites preparation is presented. LCP/PET blends were reactively extruded in presence of Pyromellitic Di-Anhydride (PMDA) and then characterized by Differential Scanning Calorimetry, Thermally Stimulated Currents and tensile mechanical properties. Moderate amounts of LCP in the PET (0.5 and 5%) and small amounts of thermo-active and reactive compatibilizer in the blend (0.3%) were found to significantly improve LCP melt dispersion, melts shear transfer and LCP fibril formation and adhesion. An unexpected improvement was probably due to the presence of two distinct phases’ supra-molecular structures involving PET-LCP and PMDA.

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