Solution combustion synthesis of LiMnPO4/C cathode material: The effect of four fuel sources on the electrochemical performances

Spinel LiMn2O4 have been prepared by the solution combustion synthesis method using acetate salts as raw materials and acetic acid as fuel. The phase compositions of the as-prepared products were determined by X-ray diffraction (XRD). The electrochemical performance of the products was tested by using a coin-type half battery versus lithium metal foil as anode material. XRD results suggested that the purities of the products prepared at 500oC are higher than these of the products prepared at 600oC. For the products prepared at 500oC, the purities of the products increase with increasing acetic acid ratios. But for the products prepared at 600oC, the purities of the products decrease with increasing acetic acid ratios. The performance tests indicated that the electrochemical performances of the products prepared at 500oC are better than these of the products prepared at 600oC. The product prepared at 500oC with the acetic acid ratio of 1.0 gets the best performance. The initial capacity of it reaches to 124.8mAh/g at the current density of 75mA/g, and after 50 cycles, the capacity retention is 93.7%.

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Ni Doped LiMn2O4 Prepared by a Flameless Combustion Synthesis

Advanced Materials Research ◽

10.4028/www.scientific.net/amr.625.251 ◽

2012 ◽

Vol 625 ◽

pp. 251-254 ◽

Cited By ~ 1

Author(s):

Gui Yang Liu ◽

Bao Sen Wang ◽

Ying He ◽

Jun Ming Guo

Keyword(s):

Combustion Synthesis ◽

Raw Materials ◽

Synthesis Method ◽

Solution Combustion Synthesis ◽

Electrochemical Performances ◽

X Ray Diffraction ◽

Galvanostatic Charge ◽

Solution Combustion ◽

Limn2o4 Spinel ◽

X Ray

In this paper, LiNixMn2−xO4 materials were prepared by solution combustion synthesis method using acetic salts as raw materials and acetic acid as fuel. The phase structures are characterized by X-ray diffraction (XRD). Electrochemical performances of the materials are investigated by galvanostatic charge/discharge methods. XRD results revealed that the main phase of the products with increasing Ni3+ content is LiMn2O4, and there is a trace amount of Mn3O4 found in the product with Ni3+ content of 0.05. Electrochemical experiments showed that the capacity and the cyclability of the LiNixMn2−xO4 materials decrease with increasing Ni3+ content. Ni3+ doping has no significantly improvement for the capacity and the cyclability of the LiMn2O4 spinel.

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Solution Combustion Synthesis of Lithium Cobalt Oxide – Cathode Material for Lithium-Ion Batteries

International Journal of Electrochemical Science ◽

10.20964/2019.03.79 ◽

2019 ◽

pp. 2965-2983 ◽

Cited By ~ 3

Author(s):

VictorD Zhuravlev ◽

Keyword(s):

Cathode Material ◽

Lithium Ion Batteries ◽

Combustion Synthesis ◽

Cobalt Oxide ◽

Lithium Ion ◽

Solution Combustion Synthesis ◽

Lithium Cobalt Oxide ◽

Solution Combustion ◽

Oxide Cathode ◽

Lithium Cobalt

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Synthesis and electrochemical performances of maricite-NaMPO4 (M = Ni, Co, Mn) electrodes for hybrid supercapacitors

RSC Advances ◽

10.1039/c4ra06050d ◽

2014 ◽

Vol 4 (95) ◽

pp. 53192-53200 ◽

Cited By ~ 59

Author(s):

Baskar Senthilkumar ◽

Kalimuthu Vijaya Sankar ◽

Leonid Vasylechko ◽

Yun-Sung Lee ◽

Ramakrishnan Kalai Selvan

Keyword(s):

Combustion Synthesis ◽

Solution Combustion Synthesis ◽

Electrochemical Performances ◽

Solution Combustion ◽

Metal Phosphates ◽

Hybrid Supercapacitors ◽

Sodium Metal

Sodium metal phosphates, NaMPO4 (M = Mn, Co and Ni) were successfully synthesized by a solution combustion synthesis (SCS) method using glycine-nitrate as a precursor.

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