Tungsten(VI) oxide supported rhodium nanoparticles: Highly active catalysts in hydrogen generation from ammonia borane

Author(s):  
Serdar Akbayrak ◽  
Yalçın Tonbul ◽  
Saim Özkar
RSC Advances ◽  
2016 ◽  
Vol 6 (107) ◽  
pp. 105940-105947 ◽  
Author(s):  
Daohua Sun ◽  
Pengyao Li ◽  
Bin Yang ◽  
Yan Xu ◽  
Jiale Huang ◽  
...  

Monodisperse AgPd alloy NPs showed remarkable catalytic activity towards the generation of hydrogen from the methanolysis of ammonia borane at room temperature.


2016 ◽  
Vol 45 (27) ◽  
pp. 10969-10978 ◽  
Author(s):  
Serdar Akbayrak ◽  
Yalçın Tonbul ◽  
Saim Özkar

Ruthenium(0) nanoparticles supported on ceria (Ru0/CeO2) were in situ generated from the reduction of ruthenium(iii) ions impregnated on ceria during the hydrolysis of ammonia borane.


RSC Advances ◽  
2014 ◽  
Vol 4 (55) ◽  
pp. 28947-28955 ◽  
Author(s):  
Halil Durak ◽  
Mehmet Gulcan ◽  
Mehmet Zahmakiran ◽  
Saim Ozkar ◽  
Murat Kaya

Nanohydroxyapatite-supported ruthenium(0) nanoparticles formed in situ during the hydrolysis of AB have been found to be a highly active catalyst in the generation of hydrogen from aqueous AB solution.


2009 ◽  
Vol 1217 ◽  
Author(s):  
Önder Metin ◽  
Saim Özkar

AbstractWater soluble poly(4-styrenesulfonic acid-co-maleic acid), PSSA-co-MA, stabilized nickel(0) and cobalt(0) nanoclusters were prepared for the first time from the reduction of nickel(II) chloride and cobalt(II) chloride by using minimum amount of sodium borohydride shortly before their usage as catalysts in the hydrolysis of ammonia-borane (AB) in the same medium at room temperature. PSSA-co-MA stabilized nickel(0) and cobalt(0) nanoclusters showed high catalytic activity in hydrogen generation from the hydrolysis of AB even at low temperature.


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