Starch based packaging materials are made from cassava starch with increased antimicrobial activity of titanium dioxide (TiO2) and zinc oxide (ZnO) nanoparticles. The objectives of this work were to evaluate the quantities of cassava starch, vinegar, glycerin, and water used for 10×10 cm2 sheet film molding, and to investigate the antimicrobial activity of starch-nanoparticles based films. TiO2 and ZnO nanoparticles were added into an aqueous starch solution at 0.01, 0.03, and 0.05 %w/w. The antimicrobial activity testing indicated that no inhibition zone against microorganisms was observable for film without the incorporation of nanoparticles. Inhibition areas were yielded by films coated with all concentrations of TiO2 and ZnO (10 mm for 1×1 cm2 and 20 mm for 2×2 cm2 dimensions of films). The results showed that starch films mixed with 0.01 %w/w of TiO2 were able to extend the shelf life of bananas from 5 - 7 days to 14 days, and tomatoes from 7 - 10 days to 21 days. The biodegradation test of starch film was carried out under the real condition of landfills. The result showed that all starch based films appeared to decompose in the soil within 14 days. The UV-vis spectrum of soil from landfill area containing nanoparticle-starch composites showed no TiO2 or ZnO absorbance spectra; there was no nanoparticle residue in soil. Starch based nanocomposite films could be used for active packaging applications for post-harvest produce.
Development of Active Biodegradable Films: Starch Films Incorporated with Starch Nanoparticles and Oregano Essential Oil
