Catalytic activity of carbon nanotube supported iron(III) and manganese(III) porphyrins in oxidation of olefins with tert-butyl hydroperoxide: Higher activity of the iron(III) porphyrin

2013 ◽  
Vol 29 ◽  
pp. 40-44 ◽  
Author(s):  
Saeed Rayati ◽  
Parisa Jafarzadeh ◽  
Saeed Zakavi
Keyword(s):  
Catalytic Activity ◽  
Carbon Nanotube ◽  
Butyl Hydroperoxide ◽  
Tert Butyl ◽  
Tert Butyl Hydroperoxide ◽  
Oxidation Of Olefins ◽  
Supported Iron

Influence of tungsten compounds on reaction of 1-octene epoxidation by tert-butyl hydroperoxide and hydroperoxide decomposition

2021 ◽  
Vol 4 (2) ◽  
pp. 23-27
Author(s):  
O. I. Makota ◽  
◽  
L. P. Oliynyk ◽  
Z. М. Komarenska ◽  
◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Tungsten Carbide ◽  
Decomposition Reaction ◽  
Butyl Hydroperoxide ◽  
Tert Butyl ◽  
Hydroperoxide Decomposition ◽  
Tert Butyl Hydroperoxide ◽  
Epoxidation Reaction ◽  
Tungsten Boride

Catalytic ability of tungsten compounds in the reaction of hydroperoxide epoxidation of 1- octene and tert-butyl hydroperoxide decomposition was investigated. It is shown that the nature of ligand has significant effect on the catalytic activity of tungsten compounds in these reactions. It is established that boride and silicide of tungsten are the best choice for epoxidation reaction, whereas tungsten carbide exhibits poor activity. Tungsten boride is also the most active in the hydroxide decomposition reaction.

scholarly journals Copper(II) Complexes of Arylhydrazone of 1H-Indene-1,3(2H)-dione as Catalysts for the Oxidation of Cyclohexane in Ionic Liquids

Catalysts ◽  
2018 ◽  
Vol 8 (12) ◽  
pp. 636 ◽  
Author(s):  
Gonçalo Tiago ◽  
Ana Ribeiro ◽  
M. C. Guedes da Silva ◽  
Kamran Mahmudov ◽  
Luís Branco ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Catalytic Activity ◽  
Ionic Liquids ◽  
Copper Complex ◽  
Butyl Hydroperoxide ◽  
Product Yields ◽  
Tert Butyl ◽  
Tert Butyl Hydroperoxide

The copper(II) complexes [CuL(H2O)2]∙H2O (1) and [CuL(dea)] (2) [L = 2-(2-(1,3-dioxo-1H-inden-2(3H)-ylidene)hydrazinyl)benzenesulfonate, dea = diethanolamine] were applied as catalysts in the peroxidative (with tert-butyl-hydroperoxide or hydrogen peroxide) conversion of cyclohexane to cyclohexanol and cyclohexanone, either in acetonitrile or in any of the ionic liquids [bmim][NTf2] and [hmim][NTf2] [bmim = 1-butyl-3-methylimidazolium, hmim = 1-hexyl-3-methylimidazolium, NTf2 = bis(trifluoromethanesulfonyl) imide]. Tert-butyl-hydroperoxide led to better product yields, as compared to H2O2, with a selectivity directed towards cyclohexanone. The ILs showed a better performance than the conventional solvent for the copper complex 1. No catalytic activity was observed for 2 in the presence of an IL.

Two catalytic systems of l-proline/Cu(ii) catalyzed allylic oxidation of olefins with tert-butyl hydroperoxide

RSC Advances ◽  
2016 ◽  
Vol 6 (70) ◽  
pp. 65403-65411 ◽  
Author(s):  
Peng Yu ◽  
Yin Zhou ◽  
Yingwei Yang ◽  
Ruiren Tang
Keyword(s):  
Catalytic System ◽  
Allylic Oxidation ◽  
Catalytic Systems ◽  
Butyl Hydroperoxide ◽  
Tert Butyl ◽  
Tert Butyl Hydroperoxide ◽  
Oxidation Of Olefins

Allylic oxidation of olefins by the two catalytic system of l-proline/Cu(ii).

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