Influence of tungsten compounds on reaction of 1-octene epoxidation by tert-butyl hydroperoxide and hydroperoxide decomposition

Catalytic ability of tungsten compounds in the reaction of hydroperoxide epoxidation of 1- octene and tert-butyl hydroperoxide decomposition was investigated. It is shown that the nature of ligand has significant effect on the catalytic activity of tungsten compounds in these reactions. It is established that boride and silicide of tungsten are the best choice for epoxidation reaction, whereas tungsten carbide exhibits poor activity. Tungsten boride is also the most active in the hydroxide decomposition reaction.

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[Ni(II) Chelates + Cetyltrimethylammonium Bromide] Composition: Characteristics of Catalytic Activity, Using the Reaction of tert-Butyl Hydroperoxide Decomposition As an Example

Russian Journal of Physical Chemistry A ◽

10.1134/s0036024421060248 ◽

2021 ◽

Vol 95 (6) ◽

pp. 1137-1142

Author(s):

L. A. Smurova ◽

Z. S. Kartasheva

Keyword(s):

Catalytic Activity ◽

Cetyltrimethylammonium Bromide ◽

Butyl Hydroperoxide ◽

Tert Butyl ◽

Hydroperoxide Decomposition ◽

Tert Butyl Hydroperoxide ◽

Composition Characteristics

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Dibenzo-18-crown-6 as a catalyst for tert-butyl hydroperoxide decomposition

Petroleum Chemistry ◽

10.1134/s0965544116020080 ◽

2016 ◽

Vol 56 (2) ◽

pp. 171-174 ◽

Cited By ~ 1

Author(s):

Kh. E. Kharlampidi ◽

N. M. Nurullina ◽

N. N. Batyrshin ◽

V. I. Anisimova ◽

I. A. Suvorova

Keyword(s):

Butyl Hydroperoxide ◽

Tert Butyl ◽

Hydroperoxide Decomposition ◽

Tert Butyl Hydroperoxide

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Pronounced catalytic activity of oxo-vanadium(IV) Schiff base complexes in the oxidation of cyclooctene and styrene by tert-butyl hydroperoxide

Comptes Rendus Chimie ◽

10.1016/j.crci.2012.05.021 ◽

2012 ◽

Vol 15 (8) ◽

pp. 679-687 ◽

Cited By ~ 28

Author(s):

Saeed Rayati ◽

Fatemeh Ashouri

Keyword(s):

Schiff Base ◽

Catalytic Activity ◽

Schiff Base Complexes ◽

Butyl Hydroperoxide ◽

Tert Butyl ◽

Tert Butyl Hydroperoxide

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ChemInform Abstract: METAL CATALYSIS IN OXIDATION BY PEROXIDES. PART 7. LIGAND EXCHANGE AND CATALYTIC ACTIVITY OF MOLYBDENUM(VI) SPECIES IN THE OXIDATION OF ORGANIC SULFIDES BY TERT-BUTYL HYDROPEROXIDE

Chemischer Informationsdienst ◽

10.1002/chin.198020242 ◽

1980 ◽

Vol 11 (20) ◽

Author(s):

F. DI FURIA ◽

G. MODENA ◽

R. CURCI ◽

J. O. EDWARDS

Keyword(s):

Catalytic Activity ◽

Ligand Exchange ◽

Metal Catalysis ◽

Butyl Hydroperoxide ◽

Tert Butyl ◽

Organic Sulfides ◽

Tert Butyl Hydroperoxide

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Copper(II) Complexes of Arylhydrazone of 1H-Indene-1,3(2H)-dione as Catalysts for the Oxidation of Cyclohexane in Ionic Liquids

Catalysts ◽

10.3390/catal8120636 ◽

2018 ◽

Vol 8 (12) ◽

pp. 636 ◽

Cited By ~ 2

Author(s):

Gonçalo Tiago ◽

Ana Ribeiro ◽

M. C. Guedes da Silva ◽

Kamran Mahmudov ◽

Luís Branco ◽

...

Keyword(s):

Hydrogen Peroxide ◽

Catalytic Activity ◽

Ionic Liquids ◽

Copper Complex ◽

Butyl Hydroperoxide ◽

Product Yields ◽

Tert Butyl ◽

Tert Butyl Hydroperoxide

The copper(II) complexes [CuL(H2O)2]∙H2O (1) and [CuL(dea)] (2) [L = 2-(2-(1,3-dioxo-1H-inden-2(3H)-ylidene)hydrazinyl)benzenesulfonate, dea = diethanolamine] were applied as catalysts in the peroxidative (with tert-butyl-hydroperoxide or hydrogen peroxide) conversion of cyclohexane to cyclohexanol and cyclohexanone, either in acetonitrile or in any of the ionic liquids [bmim][NTf2] and [hmim][NTf2] [bmim = 1-butyl-3-methylimidazolium, hmim = 1-hexyl-3-methylimidazolium, NTf2 = bis(trifluoromethanesulfonyl) imide]. Tert-butyl-hydroperoxide led to better product yields, as compared to H2O2, with a selectivity directed towards cyclohexanone. The ILs showed a better performance than the conventional solvent for the copper complex 1. No catalytic activity was observed for 2 in the presence of an IL.

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FTIR investigation into transition metal disilicides as catalysts for tert-butyl hydroperoxide decomposition

Transition Metal Chemistry ◽

10.1007/s11243-010-9333-6 ◽

2010 ◽

Vol 35 (3) ◽

pp. 345-348 ◽

Cited By ~ 1

Author(s):

Yuriy Trach ◽

Oksana Makota ◽

Jadwiga Skubiszewska-Zięba ◽

Tadeusz Borowiecki ◽

Roman Leboda

Keyword(s):

Transition Metal ◽

Butyl Hydroperoxide ◽

Tert Butyl ◽

Hydroperoxide Decomposition ◽

Tert Butyl Hydroperoxide ◽

Ftir Investigation

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Polymerization of methyl methacrylate initiated by tert-butyl hydroperoxide-sulphuric acid-acetone system

Collection of Czechoslovak Chemical Communications ◽

10.1135/cccc19840404 ◽

1984 ◽

Vol 49 (2) ◽

pp. 404-409 ◽

Cited By ~ 7

Author(s):

Jiří Pavlinec ◽

Milan Lazár

Keyword(s):

Methyl Methacrylate ◽

Sulphuric Acid ◽

Water Concentration ◽

Initial Reaction Rate ◽

Polymerization Rate ◽

Initial Reaction ◽

Butyl Hydroperoxide ◽

Tert Butyl ◽

Hydroperoxide Decomposition ◽

Tert Butyl Hydroperoxide

The radical polymerization of methyl methacrylate may be efficiently initiated by tert-butyl-hydroperoxide at 40°C and lower, deep below the temperatures of spontaneous hydroperoxide decomposition, when sulphuric acid simultaneously with ketones is used as the activator of peroxide decomposition. The initial reaction rate depends on concentration of initiator components, the exponents with regard to tert-butyl hydroperoxide, sulphuric acid and acetone being 0.25, 0.5 and 0.5, respectively. Water retards the hydroperoxide decomposition very efficiently and the polymerization rate is inversely proportional to the square root of water concentration in the system. Within the concentration range of hydroperoxide (1. 10-3 - 3. 10-2 mol dm-3), sulphuric acid 2.62 . 10-2 mol dm-3 and acetone 0.2 mol dm-3 the observed initial polymerization rate varies from 14.4%/hour to 34.5%/hour at 40°C. The concentration of water, introduced into the system by the polymerization components, was 0.05% in all cases. The activating effect of ketones upon the acid catalyzed hydroperoxide decomposition is accounted for by the formation of ketone-H2SO4 adduct that facilities the decomposition of hydroperoxide.

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