Abstract
A facile and environmentally friendly approach to produce self-doped hierachically porous carbon as electrode material for high-performance supercapacitor was demonstrated. 3D honeycomb-like hierarchically porous carbon was successfully obtained by one-step carbonization and activation of sodium carboxymethyl cellulose (CMC) via K2CO3. With the optimized temperature of carbonization and activation, the porous carbon material achieved well-shaped hierarchically pores (micro-, meso and macropores) like a honeycomb, ultrahigh specific surface area (1666 m2·g-1), as well as highly O-self-doping (3.6 at.%), endowing an excellent electrochemical properties for the electrode in three-electrode system. The porous carbon electrode material delivered a high specific capacitance of 300.8 F·g-1 at 1 A·g-1, an eminent rate capability of 228.4 F·g-1 at the current density up to 20 A·g-1 and outstanding cycle stability of 94.3% retention after 10000 cycles. Therefore, the CMC derived hierarchical porous carbon activated by K2CO3 would have promising foreground in application of supercapacitors.
Preparation and properties of porous carbon material containing magnesium oxide