Synthesis of VBO3–carbon composite by ball-milling and microwave heating and its electrochemical properties as negative electrode material of lithium ion batteries

2012 ◽  
Vol 542 ◽  
pp. 132-135 ◽  
Author(s):  
Dong-Yung Kim ◽  
Min-Sang Song ◽  
Ji-Yong Eom ◽  
Hyuk-Sang Kwon
2015 ◽  
Vol 1120-1121 ◽  
pp. 115-118 ◽  
Author(s):  
Yong Hoon Cho ◽  
Soon Ki Jeong ◽  
Yang Soo Kim

The electrochemical properties niobium dioxide (NbO2) was investigated as a negative electrode material for lithium ion batteries. The NbO2electrode showed a large irreversible capacity and small discharge capacity. The results of X-ray photoelectron spectroscopy indicate that the poor electrode performance of NbO2may be caused by niobium pentoxide (Nb2O5) formed on the surface of active material. The Nb2O5could be removed by chemical etching to some extent, thus improving the electrode performance.


2016 ◽  
Vol 835 ◽  
pp. 126-130 ◽  
Author(s):  
Kyoung Soo Park ◽  
Soon Ki Jeong ◽  
Yang Soo Kim

The electrochemical properties of niobium monoxide, NbO, were investigated as a negative electrode material for lithium-ion batteries. Lithium ions were inserted into and extracted from NbO material at potentials < 1.0 V versus Li/Li+, involving formation of a solid electrolyte interface (SEI) on the NbO surface in the first cycle. Its reversible capacity is ~67 mAh g–1 with the capacity retention of ~109% after 50 cycles. The magnitude of charge transfer resistance was greatly decreased by ball-milling the pristine NbO, whereas the ball-milling had no effect on the SEI resistance.


2018 ◽  
Vol 6 (3) ◽  
pp. 1128-1137 ◽  
Author(s):  
Shohei Maruyama ◽  
Tomokazu Fukutsuka ◽  
Kohei Miyazaki ◽  
Yumi Abe ◽  
Noriko Yoshizawa ◽  
...  

The electrochemical properties of graphitized carbon nanospheres as a promising negative electrode material for high-rate lithium-ion batteries were correlated with lithium-ion intercalation and deintercalation behaviors.


2019 ◽  
Vol 6 (11) ◽  
pp. 3196-3202
Author(s):  
Kazuhiko Mukai ◽  
Takeshi Uyama ◽  
Ikuya Yamada

To overcome the limitations of graphite as a negative electrode material for lithium-ion batteries (LIBs), transition metal oxyfluorides are under active development.


2016 ◽  
Vol 724 ◽  
pp. 87-91 ◽  
Author(s):  
Chang Su Kim ◽  
Yong Hoon Cho ◽  
Kyoung Soo Park ◽  
Soon Ki Jeong ◽  
Yang Soo Kim

We investigated the electrochemical properties of carbon-coated niobium dioxide (NbO2) as a negative electrode material for lithium-ion batteries. Carbon-coated NbO2 powders were synthesized by ball-milling using carbon nanotubes as the carbon source. The carbon-coated NbO2 samples were of smaller particle size compared to the pristine NbO2 samples. The carbon layers were coated non-uniformly on the NbO2 surface. The X-ray diffraction patterns confirmed that the inter-layer distances increased after carbon coating by ball-milling. This lead to decreased charge-transfer resistance, confirmed by electrochemical impedance spectroscopy, allowing electrons and lithium-ions to quickly transfer between the active material and electrolyte. Electrochemical performance, including capacity and initial coulombic efficiency, was therefore improved by carbon coating by ball-milling.


2020 ◽  
Vol 7 (13) ◽  
pp. 2831-2837
Author(s):  
Qingbo Xia ◽  
Pierre J. P. Naeyaert ◽  
Maxim Avdeev ◽  
Siegbert Schmid ◽  
Hongwei Liu ◽  
...  

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