Capacity degradation of Laves phase-related body-centered-cubic solid solution metal hydride alloys in battery

2019 ◽  
Vol 792 ◽  
pp. 260-266
Author(s):  
Lingkun Kong ◽  
Xinhai Li ◽  
Xingqun Liao ◽  
Xiaojuan Cai ◽  
Kwo Young
Batteries ◽  
2017 ◽  
Vol 3 (4) ◽  
pp. 27 ◽  
Author(s):  
Kwo-Hsiung Young ◽  
Shiuan Chang ◽  
Xinting Lin

2002 ◽  
Vol 753 ◽  
Author(s):  
Akiba E. ◽  
Enoki H. ◽  
Nakamura Y.

ABSTRACTHydrogen absorbing alloys with BCC (body centered cubic) structure such as Ti-V-Mn, Ti-V-Cr and Ti-V-Cr-Mn systems were proposed and named as “Laves phase related BCC solid solution” by Akiba in 1993. Since our reports, many researchers have developed BCC hydrogen absorbing alloys. These alloys have higher hydrogen capacity (about 2.8 mass% at present) than conventional intermetallic compounds. Many efforts have been made to increase hydrogen capacity of the alloys but fundamental studies were a few. Crystal structure and morphology of the BCC alloys that are keys to understand BCC hydrogen absorbing alloys are reviewed.


MRS Bulletin ◽  
2002 ◽  
Vol 27 (9) ◽  
pp. 699-703 ◽  
Author(s):  
E. Akiba ◽  
M. Okada

AbstractHydrogen-absorbing alloys with bcc (body-centered-cubic) structures, such as Ti-V-Mn, Ti-V-Cr, Ti-V-Cr-Mn, and Ti-Cr-(Mo, Ru), have been developed since 1993. These alloys have a higher hydrogen capacity (about 3.0 mass%) than conventional intermetallic hydrogen-absorbing alloys. Generally, bcc metals and alloys exhibit two plateaus in pressure–composition isotherms, but the lower plateau is far below atmospheric pressure at room temperature. Many efforts have been made to increase hydrogen capacity and raise the equilibrium pressure of this lower plateau. The crystal structure and morphology of Laves-phase-related bcc solid-solution alloys are reviewed.


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