Enhancing water splitting via weakening H2 and O2 adsorption on NiCo-LDH@CdS due to interstitial nitrogen doping: A close look at the mechanism of electron transfer

Author(s):  
Azam Pirkarami ◽  
Sousan Rasouli ◽  
Ebrahim Ghasemi
2012 ◽  
Vol 155 ◽  
pp. 165-176 ◽  
Author(s):  
Seung-Hyun Anna Lee ◽  
Yixin Zhao ◽  
Emil A. Hernandez-Pagan ◽  
Landy Blasdel ◽  
W. Justin Youngblood ◽  
...  

Author(s):  
Osamu Tomita ◽  
Hiroki Naito ◽  
Akinobu Nakada ◽  
Masanobu Higashi ◽  
Ryu Abe

Because the majority of Z-scheme water splitting systems employ a shuttle redox mediator that allows electron transfer between two photocatalyst materials, the development of an effective redox mediator is crucial...


2014 ◽  
Vol 2014 (4) ◽  
pp. 635-644 ◽  
Author(s):  
Jordan M. Sumliner ◽  
Hongjin Lv ◽  
John Fielden ◽  
Yurii V. Geletii ◽  
Craig L. Hill

2021 ◽  
pp. 3-38
Author(s):  
Jian-Ren Shen ◽  
Yoshiki Nakajima ◽  
Fusamichi Akita ◽  
Michihiro Suga

2020 ◽  
Vol 178 ◽  
pp. 391-397 ◽  
Author(s):  
Igor Moravcik ◽  
Hynek Hadraba ◽  
Linlin Li ◽  
Ivo Dlouhy ◽  
Dierk Raabe ◽  
...  

2019 ◽  
Vol 9 (12) ◽  
pp. 3099-3108 ◽  
Author(s):  
Qiuyan Hao ◽  
Shiyun Li ◽  
Hui Liu ◽  
Jing Mao ◽  
Ying Li ◽  
...  

Simultaneous carbon coating and nitrogen incorporation of a Ni3S2 nanoflake array electrocatalyst with enhanced activity and stability for water splitting.


2016 ◽  
Vol 120 (40) ◽  
pp. 23074-23082 ◽  
Author(s):  
Adriano Monti ◽  
Jessica M. de Ruiter ◽  
Huub J. M. de Groot ◽  
Francesco Buda

2008 ◽  
Vol 105 (46) ◽  
pp. 17632-17635 ◽  
Author(s):  
Javier J. Concepcion ◽  
Jonah W. Jurss ◽  
Joseph L. Templeton ◽  
Thomas J. Meyer

Light-driven water oxidation occurs in oxygenic photosynthesis in photosystem II and provides redox equivalents directed to photosystem I, in which carbon dioxide is reduced. Water oxidation is also essential in artificial photosynthesis and solar fuel-forming reactions, such as water splitting into hydrogen and oxygen (2 H2O + 4 hν → O2 + 2 H2) or water reduction of CO2 to methanol (2 H2O + CO2 + 6 hν → CH3OH + 3/2 O2), or hydrocarbons, which could provide clean, renewable energy. The “blue ruthenium dimer,” cis,cis-[(bpy)2(H2O)RuIIIORuIII(OH2)(bpy)2]4+, was the first well characterized molecule to catalyze water oxidation. On the basis of recent insight into the mechanism, we have devised a strategy for enhancing catalytic rates by using kinetically facile electron-transfer mediators. Rate enhancements by factors of up to ≈30 have been obtained, and preliminary electrochemical experiments have demonstrated that mediator-assisted electrocatalytic water oxidation is also attainable.


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