Electrochemical oxidation of graphite in aqueous hydrofluoric acid solution at high current densities

2016 ◽  
Vol 185 ◽  
pp. 36-41 ◽  
Author(s):  
Yoshiaki Matsuo ◽  
Saeko Hirata ◽  
Marc Dubois
Keyword(s):  
Acid Solution ◽  
Electrochemical Oxidation ◽  
Hydrofluoric Acid ◽  
Hydrofluoric Acid Solution ◽  
High Current ◽  
Current Densities

Enthalpic analysis of the CaTiSiO5 system

2006 ◽  
Vol 60 (4) ◽  
Author(s):  
I. Nerád ◽  
L. Kosa ◽  
E. Mikšíková ◽  
K. Adamkovičová
Keyword(s):  
Experimental Data ◽  
Acid Solution ◽  
Hydrofluoric Acid ◽  
Solution Calorimetry ◽  
Enthalpy Of Fusion ◽  
Drop Calorimetry ◽  
Enthalpies Of Solution ◽  
Hydrofluoric Acid Solution ◽  
Relative Enthalpy

AbstractThe relative enthalpy of titanite and enthalpy of CaTiSiO5 melt have been measured using drop calorimetry between 823 K and 1843 K. Enthalpies of solution of titanite and CaTiSiO5 glass have been measured by the use of hydrofluoric acid solution calorimetry at 298 K. Enthalpy of vitrification at 298 K, δvitr H(298 K) = (80.7 ± 3.4) kJ mol−1, and enthalpy of fusion at the temperature of fusion 1656 K, δfus H(1656 K) = (139 ± 3) kJ mol−1, of titanite have been determined from experimental data. The obtained enthalpy of fusion is considerably higher than up to the present published values of this quantity.

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