scholarly journals Normalized polarity indices of tri-n-butyl phosphate metal complexes in ionic liquid using Reichardt's dye as polarity probe

2021 ◽  
pp. 100014
Author(s):  
Ch. Venkateswara Rao ◽  
Alok Rout ◽  
K.A. Venkatesan
Keyword(s):  
Ionic Liquid ◽  
Metal Complexes ◽  
Reichardt’S Dye

scholarly journals Polynuclear Metal Complexes Obtained from the Task-Specific Ionic Liquid Betainium Bistriflimide

2008 ◽  
Vol 8 (4) ◽  
pp. 1353-1363 ◽  
Author(s):  
Peter Nockemann ◽  
Ben Thijs ◽  
Kristof Van Hecke ◽  
Luc Van Meervelt ◽  
Koen Binnemans
Keyword(s):  
Ionic Liquid ◽  
Metal Complexes ◽  
Polynuclear Metal Complexes ◽  
Task Specific Ionic Liquid

Schiff base ligands and their transition metal complexes in the mixtures of ionic liquid + organic solvent: a thermodynamic study

2015 ◽  
Vol 17 (3) ◽  
pp. 2179-2191 ◽  
Author(s):  
Hemayat Shekaari ◽  
Amir Kazempour ◽  
Maryam Khoshalhan
Keyword(s):  
Ionic Liquid ◽  
Schiff Base ◽  
Transition Metal ◽  
Organic Solvent ◽  
Metal Complexes ◽  
Binary Mixtures ◽  
Transition Metal Complexes ◽  
Schiff Base Complex ◽  
Partial Molar Volumes ◽  
Schiff Base Ligands

Standard partial molar volumes (V0ϕ,IL) of the IL [HMIm]Cl in the binary mixtures of a Schiff base complex + DMF at T = 298.15 to 313.15 K.

Silica Gel Confined Ionic Liquid+Metal Complexes for Oxygen-Free Carbonylation of Amines and Nitrobenzene to Ureas

2005 ◽  
Vol 347 (2-3) ◽  
pp. 225-230 ◽  
Author(s):  
Feng Shi ◽  
Qinghua Zhang ◽  
Yanlong Gu ◽  
Youquan Deng
Keyword(s):  
Ionic Liquid ◽  
Liquid Metal ◽  
Metal Complexes ◽  
Silica Gel

Metal Complexes of an Ionic Liquid-Derived Carbene

2011 ◽  
Vol 64 (8) ◽  
pp. 1133 ◽  
Author(s):  
Marcus L. Cole ◽  
Matthew R. Gyton ◽  
Jason B. Harper
Keyword(s):  
Carbon Monoxide ◽  
Ionic Liquid ◽  
Metal Complexes ◽  
Silver Salt ◽  
Ligand Substitution ◽  
Molecular Structures ◽  
Direct Reaction ◽  
Metal Acetate ◽  
Carbene Complexes ◽  
Hydrochloride Salt

A range of metal carbene complexes containing the ionic liquid-derived N-heterocyclic carbene (NHC) 1-nbutyl-3-methylimidazol-2-ylidene (IBuMe, 1) have been prepared by (i) direct ligand substitution using the free NHC ([Mo(CO)5(IBuMe)] 2), (ii) transmetallation using the silver salt [AgCl(IBuMe)] (3) ([RhCl(NBD)(IBuMe)] (4) and [IrCl(COD)(IBuMe)] (5), NBD = 2,5-norbornadiene, COD = 1,5-cyclooctadiene) and (iii) direct reaction of a metal acetate with the hydrochloride salt of 1 (trans-[PdCl2(IBuMe)] (6)). The dicarbonyl cis-[RhCl(CO)2(IBuMe)] (7) has been prepared by diene substitution under a carbon monoxide atmosphere. The molecular structures of 2, 4, 5 and 6 are reported and the sigma donation and steric properties of 1 are discussed relative to those of common imidazol-2-ylidene ligands.

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