Instrumentation for solid-state dynamic nuclear polarization with magic angle spinning NMR

2016 ◽  
Vol 264 ◽  
pp. 88-98 ◽  
Author(s):  
Melanie Rosay ◽  
Monica Blank ◽  
Frank Engelke
Keyword(s):  
Solid State ◽  
Dynamic Nuclear Polarization ◽  
Nuclear Polarization ◽  
Magic Angle Spinning ◽  
Magic Angle ◽  
State Dynamic ◽  
Angle Spinning

scholarly journals Photo-CIDNP in Solid State

2021 ◽  
Author(s):  
Jörg Matysik ◽  
Yonghong Ding ◽  
Yunmi Kim ◽  
Patrick Kurle ◽  
Alexandra Yurkovskaya ◽  
...  
Keyword(s):  
Solid State ◽  
Dynamic Nuclear Polarization ◽  
Analytical Method ◽  
Nuclear Polarization ◽  
State Of The Art ◽  
Magic Angle Spinning ◽  
Magic Angle ◽  
Radical Pairs ◽  
Chemically Induced ◽  
Angle Spinning

AbstractPhoto-CIDNP (photo-chemically induced dynamic nuclear polarization) refers to nuclear polarization created by the spin-chemical evolution of spin-correlated radical pairs (SCRPs). This phenomenon occurs in gases, liquids and solids. Based on the solid-state photo-CIDNP effect observed under magic-angle spinning (MAS), photo-CIDNP MAS NMR has been developed as analytical method. Here we report the origin, the theory and the state of the art of this method.

scholarly journals Optimizing nitroxide biradicals for cross-effect MAS-DNP: the role of g-tensors’ distance

2020 ◽  
Vol 22 (6) ◽  
pp. 3643-3652 ◽  
Author(s):  
Frédéric Mentink-Vigier
Keyword(s):  
Solid State ◽  
Dynamic Nuclear Polarization ◽  
Solid State Nmr ◽  
Nuclear Polarization ◽  
Magic Angle Spinning ◽  
Magic Angle ◽  
Cross Effect ◽  
Angle Spinning

Nitroxide biradicals are common polarizing agents used to enhance the sensitivity of solid-state NMR experiments via Magic Angle Spinning Dynamic Nuclear Polarization (MAS-DNP).

scholarly journals Natural Abundance Oxygen-17 Solid-State NMR of Metal Organic Frameworks Enhanced by Dynamic Nuclear Polarization

2021 ◽  
Author(s):  
Diego Carnevale ◽  
Georges Mouchaham ◽  
Sujing WANG ◽  
Mathieu Baudin ◽  
Christian SERRE ◽  
...  
Keyword(s):  
Solid State ◽  
Nmr Spectroscopy ◽  
Dynamic Nuclear Polarization ◽  
Solid State Nmr ◽  
Nuclear Polarization ◽  
Metal Organic Frameworks ◽  
Magic Angle Spinning ◽  
Magic Angle ◽  
Metal Organic ◽  
Angle Spinning

The 17O resonances of Zirconium-oxo clusters in porous Zr carboxylate metal-organic frameworks (MOFs) have been investigated by magic-angle spinning (MAS) NMR spectroscopy enhanced by dynamic nuclear polarization (DNP) at natural...

scholarly journals Measurement of 14N quadrupole couplings in biomolecular solids using indirect-detection 14N solid-state NMR with DNP

2017 ◽  
Vol 53 (89) ◽  
pp. 12116-12119 ◽  
Author(s):  
J. A. Jarvis ◽  
I. Haies ◽  
M. Lelli ◽  
A. J. Rossini ◽  
I. Kuprov ◽  
...  
Keyword(s):  
Protein Structure ◽  
Solid State ◽  
Dynamic Nuclear Polarization ◽  
Solid State Nmr ◽  
Nuclear Polarization ◽  
Magic Angle Spinning ◽  
Indirect Detection ◽  
Magic Angle ◽  
Angle Spinning

Insights into protein structure through the determination of 14N quadrupolar interactions using magic-angle spinning dynamic nuclear polarization NMR.

scholarly journals Dynamic nuclear polarization at 40 kHz magic angle spinning

2016 ◽  
Vol 18 (15) ◽  
pp. 10616-10622 ◽  
Author(s):  
Sachin R. Chaudhari ◽  
Pierrick Berruyer ◽  
David Gajan ◽  
Christian Reiter ◽  
Frank Engelke ◽  
...  
Keyword(s):  
Solid State ◽  
Nmr Spectroscopy ◽  
Dynamic Nuclear Polarization ◽  
Solid State Nmr ◽  
Nuclear Polarization ◽  
Magic Angle Spinning ◽  
Magic Angle ◽  
Solid State Nmr Spectroscopy ◽  
Wide Range ◽  
Angle Spinning

DNP-enhanced solid-state NMR spectroscopy is shown to maintain performance over a wide range of sample spinning rates up to 40 kHz.

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